I noticed this typo in ions.itp under the FF_OPLS section. It appears to have been present at least from 3.2.1 to 3.3.3 (the atom name for LI+ is NA) [ moleculetype ] ; molname nrexcl LI+ 1 [ atoms ] ; id at type res nr residu name at name cg nr charge mass 1 opls_406 1 LI+ NA 1 1 6.941