[gmx-users] OPLS force field does not recognize Atom type

Justin A. Lemkul jalemkul at vt.edu
Tue Sep 9 22:30:24 CEST 2008



Morteza Khabiri wrote:
> Dear
> I want to make the solution which is not working with unified atom force
> fields. Then I decided to make the itp file by my own.
> I made the all atom type ....itp file for opls AA. I found all of the opls
> feature in gromacs top directory and according to the top directory files
> I made the new itp file. Unfortunately, after running the grompp i faced
> with the following error:
>    Fatal error:
>                    Atomtype 'HC' not found!
> but it is defined in the opls.
> 

How so?  If you look in ffoplsaa.atp, you will note that all atomtypes are 
defined as opls_XXX.

-Justin

> My itp file structure is like follow:
> ;
> [ moleculetype ]
> ; Name nrexcl
> DRG      3
> 
> [ atoms ]
> ;   nr      type  resnr resid  atom  cgnr   charge     mass
>      1        HC     1  DRG     HAD     1    0.02734   1.0080
>      2        CT     1  DRG     CAL     1    0.10638  12.0110
>      3        HC     1  DRG     HAE     1    0.02734   1.0080
>      4        OS     1  DRG     OAI     1   -0.36111  15.9994
>      5        CT     1  DRG     CAK     1    0.10638  12.0110
>      6        HC     1  DRG     HAB     2    0.02734   1.0080
>      7        HC     1  DRG     HAG     2    0.02734   1.0080
>      8        CY     1  DRG     CAM     2    0.00235  12.0110
>      9        HC     1  DRG     HAF     3    0.00857   1.0080
>     10        HC     1  DRG     HAH     3    0.00857   1.0080
>     11        CY     1  DRG     CAJ     3    0.00235  12.0110
>     12        HC     1  DRG     HAC     3    0.00857   1.0080
>     13        HC     1  DRG     HAA     3    0.00857   1.0080
> 
> [ bonds ]
> ; ai  aj  fu    c0, c1, ...
>    1   2   1    0.109    284512.0    0.109    284512.0 ;   HAD  CAL
>    2   3   1    0.109    284512.0    0.109    284512.0 ;   CAL  HAE
>    2   4   1    0.141    267776.0    0.141    267776.0 ;   CAL  HAI
>    2  11   1    0.152    217568.0    0.152    217568.0 ;   CAL  CAJ
>    4   5   1    0.141    267776.0    0.141    267776.0 ;   OAI  CAK
>    5   6   1    0.109    284512.0    0.109    284512.0 ;   CAK  HAB
>    5   7   1    0.109    284512.0    0.109    284512.0 ;   CAK  HAG
>    5   8   1    0.151    234304.0    0.151    234304.0 ;   CAK  CAM
>    8   9   1    0.108    284512.0    0.108    284512.0 ;   CAM  HAF
>    8  10   1    0.108    284512.0    0.108    284512.0 ;   CAM  HAH
>    8  11   1    0.150    217568.0    0.150    217568.0 ;   CAM  CAJ
>   11  12   1    0.108    284512.0    0.108    284512.0 ;   CAJ  HAC
>   11  13   1    0.108    284512.0    0.108    284512.0 ;   CAJ  HAA
> 
> [ pairs ]
> ; ai  aj  fu    c0, c1, ...
>    1   5   1                                           ;   HAD  CAK
>    1   8   1                                           ;   HAD  CAM
>    1  12   1                                           ;   HAD  HAC
>    1  13   1                                           ;   HAD  HAA
>    2   6   1                                           ;   CAL  HAB
>    2   7   1                                           ;   CAL  HAG
>    2   9   1                                           ;   CAL  HAF
>    2  10   1                                           ;   CAL  HAH
>    3   5   1                                           ;   HAE  CAK
>    3   8   1                                           ;   HAE  CAM
>    3  12   1                                           ;   HAE  HAC
>   6   9   1                                           ;   HAB  HAF
>    8  10   1                                           ;   HAB  HAH
>    6  11   1                                           ;   HAB  CAJ
>    7   9   1                                           ;   HAG  HAF
>    7  10   1                                           ;   HAG  HAH
>    7  11   1                                           ;   HAG  CAJ
>    9  12   1                                           ;   HAF  HAC
>    9  13   1                                           ;   HAF  HAA
>   10  12   1                                           ;   HAH  HAC
>   10  13   1                                           ;   HAH  HAA
> 
> [ angles ]
> ; ai  aj  ak  fu    c0, c1, ...
>    1   2   3   1    107.8       276.1    107.8       276.1 ;   HAD  CAL  HAE
>    1   2   4   1    109.5       292.8    109.5       292.8 ;   HAD  CAL  OAI
>    1   2  11   1    110.7       313.8    109.5       397.5 ;   HAD  CAL  CAJ
>    3   2   4   1    109.5       292.8    109.5       292.8 ;   HAE  CAL  OAI
>    3   2  11   1    110.7       313.8    110.7       313.8 ;   HAE  CAL  CAJ
>    4   2  11   1    109.5       292.8    109.5       292.8 ;   OAI  CAL  CAJ
>    2   4   5   1    109.5       502.0    109.5       502.0 ;   CAL  OAI  CAK
>    4   5   6   1    109.5       292.8    109.5       292.8 ;   OAI  CAK  HAB
>    4   5   7   1    109.5       292.8    109.5       292.8 ;   OAI  CAK  HAG
>    4   5   8   1    109.5       292.8    109.5       292.8 ;   OAI  CAK  CAM
>    6   5   7   1    107.8       276.1    107.8       276.1 ;   HAB  CAK  HAG
>    6   5   8   1    110.7       313.8    110.7       313.8 ;   HAB  CAK  CAM
>    7   5   8   1    110.7       313.8    110.7       313.8 ;   HAG  CAK  CAM
>    5   8   9   1    114.3       292.8    114.3       292.8 ;   CAK  CAM  HAF
>    5   8  10   1    114.3       292.8    114.3       292.8 ;   CAK  CAM  HAH
>    5   8  11   1    117.2       313.8    117.2       313.8 ;   CAK  CAM  CAJ
>    9   8  10   1    114.3       292.8    114.3       292.8 ;   HAF  CAM  HAH
>    9   8  11   1    117.2       313.8    117.2       313.8 ;   HAF  CAM  CAJ
>   10   8  11   1    117.2       313.8    117.2       313.8 ;   HAH  CAM  CAJ
>    2  11   8   1    117.2       313.8    117.2       313.8 ;   CAL  CAJ  CAM
>    2  11  12   1    114.3       292.8    114.3       292.8 ;   CAL  CAJ  HAC
>    2  11  13   1    114.3       292.8    114.3       292.8 ;   CAL  CAJ  HAA
>    8  11  12   1    117.2       313.8    117.2       313.8 ;   CAM  CAJ  HAC
>    8  11  13   1    117.2       313.8    117.2       313.8 ;   CAM  CAJ  HAA
>   12  11  13   1    114.3       292.8    114.3       292.8 ;   HAC  CAJ  HAA
> 
> [ dihedrals ]
> ; ai  aj  ak  al  fu    c0, c1, m, ...
>    2   1   3   4   3     1.58  4.769       1.58  4.769   ; imp   CAL  HAD 
> HAE  OAI
>    5   4   6   7   3     1.58  4.769       1.58  4.769   ; imp   CAK  OAI 
> HAB  HAG
>    8   5  10   9   3     0.62  1.882       0.62  1.882   ; imp   CAM  CAK 
> HAH  HAF
>   11   2  12   8   3     0.62  1.882       0.62  1.882   ; imp   CAJ  CAL 
> HAC  CAM
>    1   2   4   5   3      1.5    4.7 3      1.5    4.7 3 ; dih   HAD  CAL 
> OAI  CAK
>   13  11   2   1   3      1.5    4.7 3      1.5    4.7 3 ; dih   HAA  CAJ 
> CAL  HAD
>    2   4   5   8   3      1.5    4.7 3      1.5    4.7 3 ; dih   CAL  OAI 
> CAK  CAM
>   11   8   5   4   3      1.5    4.7 3      1.5    4.7 3 ; dih   CAJ  CAM 
> CAK  OAI
>   13  11   8   5   3      0.6    1.8 3      0.6    1.8 3 ; dih   HAA  CAJ 
> CAM  CAK
> 
> 
> The top file is also set to OPLS forcefield.
> 
> I don't know what is wrong exactly. Thats very nice of you if you could
> help me.
> 
> Thank you very much in advance
> 
> Morteza
> 
> 
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-- 
========================================

Justin A. Lemkul
Graduate Research Assistant
Department of Biochemistry
Virginia Tech
Blacksburg, VA
jalemkul[at]vt.edu | (540) 231-9080
http://www.bevanlab.biochem.vt.edu/Pages/Personal/justin

========================================



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