[gmx-users] Implicit solvent - Gromacs 4.5.4

Justin A. Lemkul jalemkul at vt.edu
Tue Feb 28 15:13:21 CET 2012



lina wrote:
> On Tue, Feb 28, 2012 at 10:07 PM, Steven Neumann <s.neumann08 at gmail.com> wrote:
>> Thank you Vedat!
>>
>> Why do you use -DFLEXIBLE in md and in em?
>> Why dont you use constraint algorithm (LINCS) in your simulation?
> 
> Otherwise, the system is easily explode with lots of LINCS warning.
> 

A system that is unstable will cause the LINCS algorithm to fail, but turning 
off constraints does not prevent a system from becoming unstable or crashing.

-Justin

> Also thanks Vedat for sharing,
> 
> Best regards,
> 
>> Steven
>>
>> On Tue, Feb 28, 2012 at 12:14 PM, Vedat Durmaz <durmaz at zib.de> wrote:
>>>
>>> hi steven,
>>>
>>> i've been simulating a 33 AA peptide for the past two days using implicent
>>> solvent in order to achieve a proper folding.
>>>
>>> i haven't added counterions, however, the systems shows nice results
>>> according to what i've expected. the mdrun command (for the extension) for
>>> our hardware looks as follows:
>>>
>>> mpiexec -np 4 mdrun -pd -s md.tpr -append -cpi md.cpt -deffnm md 2>&1
>>>
>>> and here's the mdp file for the energy minimization:
>>>
>>> define              =  -DFLEXIBLE
>>> constraints         =  none
>>> integrator          =  steep
>>> dt                  =  0.001    ; ps
>>> nsteps              =  30000
>>> vdwtype             =  cut-off
>>> coulombtype         =  cut-off
>>> pbc                 =  no
>>> nstlist             =  0
>>> ns_type             =  simple
>>> rlist               =  0       ; this means all-vs-all (no cut-off), which
>>> gets expensive for bigger systems
>>> rcoulomb            =  0
>>> rvdw                =  0
>>> comm-mode           =  angular
>>> comm-grps           =  Protein
>>> optimize_fft        =  yes
>>> ;
>>> ;       Energy minimizing stuff
>>> ;
>>> emtol               =  5.0
>>> emstep              =  0.01
>>> ;
>>> ; Implicit solvent
>>> ;
>>> implicit_solvent    =  GBSA
>>> gb_algorithm        =  Still ; HCT ; OBC
>>> nstgbradii          =  1
>>> rgbradii            =  0   ; [nm] Cut-off for the calculation of the Born
>>> radii. Currently must be equal to rlist
>>> gb_epsilon_solvent  =  80    ; Dielectric constant for the implicit
>>> solvent
>>> ; gb_saltconc       =  0     ; Salt concentration for implicit solvent
>>> models, currently not used
>>> sa_algorithm        =  Ace-approximation
>>> sa_surface_tension  = -1
>>>
>>>
>>> and for the md run:
>>>
>>> define              =  -DPOSRESHELIX ; -DFLEXIBLE -DPOSRES
>>> constraints         =  none
>>> integrator          =  md
>>> dt                  =  0.001   ; ps
>>> nsteps              =  1000000000 ; 100000 ps = 100 ns
>>> nstcomm             =  10
>>> nstcalcenergy       =  10
>>> nstxout             =  1000     ; frequency to write coordinates to output
>>> trajectory
>>> nstvout             =  0       ; frequency to write velocities to output
>>> trajectory; the last velocities are always written
>>> nstfout             =  0       ; frequency to write forces to output
>>> trajectory
>>> nstlog              =  1000         ; frequency to write energies to log
>>> file
>>> nstenergy           =  1000     ; frequency to write energies to edr file
>>>
>>> vdwtype             =  cut-off
>>> coulombtype         =  cut-off
>>>
>>> pbc                 =  no
>>>
>>> nstlist             =  0
>>> ns_type             =  simple
>>> rlist               =  0       ; this means all-vs-all (no cut-off), which
>>> gets expensive for bigger systems
>>> rcoulomb            =  0
>>> rvdw                =  0
>>>
>>> comm-mode           =  angular
>>> comm-grps           =  system
>>>
>>> optimize_fft        =  yes
>>>
>>> ; V-rescale temperature coupling is on
>>> Tcoupl              =  v-rescale
>>> tau_t               =  0.1
>>> tc_grps             =  system
>>> ref_t               =  300
>>> ; Pressure coupling is off
>>> Pcoupl              =  no
>>> ; Generate velocites is on
>>> gen_vel             =  yes
>>> gen_temp            =  300
>>> gen_seed            =  -1
>>>
>>> ;
>>> ; Implicit solvent
>>> ;
>>> implicit_solvent    =  GBSA
>>> gb_algorithm        =  Still ; HCT ; OBC
>>> nstgbradii          =  1
>>> rgbradii            =  0   ; [nm] Cut-off for the calculation of the Born
>>> radii. Currently must be equal to rlist
>>> gb_epsilon_solvent  =  80    ; Dielectric constant for the implicit
>>> solvent
>>> ; gb_saltconc       =  0     ; Salt concentration for implicit solvent
>>> models, currently not used
>>> sa_algorithm        =  Ace-approximation
>>> sa_surface_tension  = -1
>>>
>>>
>>> best regards,
>>> vedat
>>>
>>>
>>> Am 28.02.2012 11:59, schrieb Steven Neumann:
>>>
>>>> Dear Gmx Users,
>>>> I am using Gromacs 4.5.4 and I would like to implement implicit solvent
>>>> for folding of my protein. I read mailing list and it is still confusing for
>>>> me.
>>>> Is it proper to use counterions within the system? If not, how can I
>>>> obtain netral system?
>>>> Do we use cut off for vdw and coulombic interactions?
>>>> What kind of integrator should be used with a timestep?
>>>> I will appreciate an mdp file for protein folding! Thank you
>>>> Steven
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>>
>>
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-- 
========================================

Justin A. Lemkul
Ph.D. Candidate
ICTAS Doctoral Scholar
MILES-IGERT Trainee
Department of Biochemistry
Virginia Tech
Blacksburg, VA
jalemkul[at]vt.edu | (540) 231-9080
http://www.bevanlab.biochem.vt.edu/Pages/Personal/justin

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