[gmx-users] Error during npt equilibration in coarse grained simulation

Justin Lemkul jalemkul at vt.edu
Tue Feb 26 12:53:34 CET 2013



On 2/26/13 12:51 AM, Anu Chandran wrote:
>   Sir,
> I have tried Berendsen barostat for Pcoupl. Still I get the same error.
>

So have a look at the other recommendations on the page I linked.  Thermostat 
instability is just one possibility.  We have had numerous reports, just in the 
last week, of crashes with CG force fields during equilibration (hint: check the 
archives).  You probably need either better minimization or a shorter time step.

-Justin

> On Mon, Feb 25, 2013 at 6:58 PM, Justin Lemkul <jalemkul at vt.edu> wrote:
>
>>
>>
>> On 2/25/13 12:16 AM, Anu Chandran wrote:
>>
>>> Dear users,
>>> I am trying to do a coarse grained simulation of an octamer of a 350
>>> residue protein in water using gromacs-4.5.3 using martini force field. I
>>> got the following error when i started running NPT equilibration
>>>
>>> "Step 32, time 0.64 (ps)  LINCS WARNING
>>> relative constraint deviation after LINCS:
>>> rms 16.561310, max 137.568573 (between atoms 626 and 627)
>>> bonds that rotated more than 30 degrees:
>>>    atom 1 atom 2  angle  previous, current, constraint length
>>>
>>> Step 32, time 0.64 (ps)  LINCS WARNING
>>> relative constraint deviation after LINCS:
>>> rms 438.087891, max 3717.233887 (between atoms 580 and 581)
>>> bonds that rotated more than 30 degrees:
>>>    atom 1 atom 2  angle  previous, current, constraint length
>>>       626    627  121.9    0.2705  36.7207      0.2650
>>>       621    622   90.0    0.2756   0.4600      0.2700
>>>       624    626   91.5    0.3368 269.7515      0.3300
>>>       621    623   90.0    0.2756   0.3172      0.2700
>>>       620    624   90.4    0.3164 432.6003      0.3100
>>>       622    623   90.0    0.2756   0.3991      0.2700
>>>       618    620   85.5    0.3164 477.1006      0.3100
>>>       626    627  121.9    0.2705  36.7206      0.2650
>>>       615    618   88.6    0.3164 211.2461      0.3100
>>>       607    610  141.3    0.3164  14.3253      0.3100
>>>
>>> Step 32, time 0.64 (ps)  LINCS WARNING
>>> relative constraint deviation after LINCS:
>>> rms 134.347206, max 2000.691284 (between atoms 4949 and 4946)
>>> bonds that rotated more than 30 degrees:
>>>    atom 1 atom 2  angle  previous, current, constraint length
>>>       610    612  149.2    0.3164  17.6610      0.3100
>>>       612    614   89.7    0.3164   3.1394      0.3100
>>>       614    615  150.9    0.3164   9.9306      0.3100
>>>       615    618   88.6    0.3164 211.1131      0.3100
>>>       618    620   85.5    0.3164 477.0737      0.3100
>>>       620    624   90.4    0.3164 432.5994      0.3100
>>>      4950   4949   75.8    0.3164 146.5132      0.3100
>>>       624    626   91.5    0.3368 269.7514      0.3300
>>>      4952   4950  118.9    0.3164  14.6303      0.3100
>>>       468    469   90.0    0.2705  24.6834      0.2650
>>>      4941   4939   90.0    0.3368   8.5601      0.3300
>>>       585    586   61.3    0.2756   0.3361      0.2700
>>>      4944   4941   82.5    0.3164 206.9830      0.3100
>>>       586    587   90.1    0.2756   0.3137      0.2700
>>>      4946   4944   90.0    0.3164 583.5660      0.3100
>>>       606    607   90.0    0.3368   6.6314      0.3300
>>>      4949   4946   90.0    0.3164 620.5243      0.3100
>>>       580    581   91.9    0.4030 1003.9232      0.2700
>>>      4954   4952   90.3    0.3164   1.6571      0.3100
>>>       580    582   89.8    0.2756 960.9988      0.2700
>>>       582    583   98.6    0.2756 592.0677      0.2700
>>>       463    464   90.0    0.2654   7.6858      0.2600
>>>       581    582   88.8    0.1280 193.0707      0.2700
>>>       581    583   91.3    0.2254 514.1149      0.2700
>>> Wrote pdb files with previous and current coordinates
>>> Wrote pdb files with previous and current coordinates
>>> Segmentation fault (core dumped)"
>>>
>>>
>>> Energy minimization and the NVT equilibration ran without any error or
>>> warning. The mdp file used is as shown below;
>>>
>>> title                    = Martini
>>> define                   = -DPOSRES
>>> integrator               = md
>>> dt                       = 0.02
>>> nsteps                   = 50000
>>> nstcomm                  = 10
>>> comm-grps                =
>>> nstxout                  = 0
>>> nstvout                  = 0
>>> nstfout                  = 0
>>> nstlog                   = 1000
>>> nstenergy                = 100
>>> nstxtcout                = 1000
>>> xtc_precision            = 100
>>> xtc-grps                 =
>>> energygrps               = Protein W
>>> nstlist                  = 10
>>> ns_type                  = grid
>>> pbc                      = xyz
>>> rlist                    = 1.4
>>> coulombtype              = Shift
>>> rcoulomb_switch          = 0.0
>>> rcoulomb                 = 1.2
>>> epsilon_r                = 15
>>> vdw_type                 = Shift
>>> rvdw_switch              = 0.9
>>> rvdw                     = 1.2
>>> tcoupl                   = v-rescale
>>> tc-grps                  = System
>>> tau_t                    = 1.0
>>> ref_t                    = 300
>>> Pcoupl                   = parrinello-rahman
>>> Pcoupltype               = isotropic
>>> tau_p                    = 5.0
>>> compressibility          = 3e-4
>>> ref_p                    = 1.0
>>> gen_vel                  = yes
>>>
>>
>> If you ran NVT previously, regenerating velocities defeats that purpose
>> and perturbs the system unnecessarily.  Further, Parrinello-Rahman is not
>> very stable for initial equilibration; use Berendsen and then switch to P-R
>> for data collection.
>>
>>
>>   gen_temp                 = 300
>>> gen_seed                 = 473529
>>> constraints              = none
>>> constraint_algorithm     = Lincs
>>> unconstrained_start      = no
>>> lincs_order              = 4
>>> lincs_warnangle          = 30
>>>
>>> Also the water box after energy minimization showed some gaps towards the
>>> edge of the box when visualized using VMD.
>>>
>>>
>>> can anybody please help me on how to overcome this error?
>>>
>>>
>> In addition to the above, see the standard advice for unstable systems:
>>
>> http://www.gromacs.org/**Documentation/Terminology/**Blowing_Up<http://www.gromacs.org/Documentation/Terminology/Blowing_Up>
>>
>> -Justin
>>
>> --
>> ==============================**==========
>>
>> Justin A. Lemkul, Ph.D.
>> Research Scientist
>> Department of Biochemistry
>> Virginia Tech
>> Blacksburg, VA
>> jalemkul[at]vt.edu | (540) 231-9080
>> http://www.bevanlab.biochem.**vt.edu/Pages/Personal/justin<http://www.bevanlab.biochem.vt.edu/Pages/Personal/justin>
>>
>> ==============================**==========
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-- 
========================================

Justin A. Lemkul, Ph.D.
Research Scientist
Department of Biochemistry
Virginia Tech
Blacksburg, VA
jalemkul[at]vt.edu | (540) 231-9080
http://www.bevanlab.biochem.vt.edu/Pages/Personal/justin

========================================



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