[gmx-users] LINCS warning

Justin Lemkul jalemkul at vt.edu
Mon Apr 28 12:23:34 CEST 2014



On 4/28/14, 1:37 AM, Gaurav Saraf IDD M Tech Biochem. Engg, IIT (BHU) wrote:
> Dear Gromacs user,
>
> After I give the command for nvt, I get the following error:
> starting mdrun 'Protein in water'
> 150000 steps,    300.0 ps.
>
> Step 0, time 0 (ps)  LINCS WARNING

If the run crashes at step zero, it suggests a catastrophic failure, i.e. the 
input configuration is not stable enough to simulate or there is a topology problem.

> relative constraint deviation after LINCS:
> rms 0.410417, max 7.601056 (between atoms 188 and 192)
> bonds that rotated more than 30 degrees:
>   atom 1 atom 2  angle  previous, current, constraint length
>      177    179   40.7    0.1342   0.2195      0.1330
>      179    181   69.6    0.1484   0.2977      0.1470
>      179    180   51.1    0.1005   0.1744      0.1000
>      181    195   75.8    0.1543   0.2575      0.1530
>      181    182   77.0    0.1549   0.6596      0.1530
>      182    183   47.8    0.1549   0.3570      0.1530
>      183    186   76.8    0.1407   1.1049      0.1390
>      183    184   76.1    0.1406   0.9974      0.1390
>      186    187   69.8    0.1097   0.3696      0.1090
>      188    192   79.1    0.1403   1.1955      0.1390
>      188    189   72.0    0.1099   0.3759      0.1090
>      190    192   77.9    0.1404   1.1212      0.1390
>      190    191   71.5    0.1099   0.3818      0.1090
>      195    197   34.8    0.1345   0.1997      0.1330
>      195    196   39.9    0.1237   0.1807      0.1230
>     4571   4569   40.0    0.1404   0.0953      0.1400
>     4570   4569   91.2    0.1245   0.1846      0.1230
>     4572   4571   31.3    0.1005   0.1253      0.1000
>      184    188   41.1    0.1397   0.2396      0.1390
>      184    185   72.1    0.1097   0.4012      0.1090
>      193    194   82.9    0.1015   0.6012      0.1000
> Wrote pdb files with previous and current coordinates
> step 0
> Step 1, time 0.002 (ps)  LINCS WARNING
> relative constraint deviation after LINCS:
> rms 2524.656192, max 85802.020979 (between atoms 170 and 177)
> bonds that rotated more than 30 degrees:
>   atom 1 atom 2  angle  previous, current, constraint length
>      170    177   81.9    0.1793 13127.8622      0.1530
>      177    179   94.9    0.2195 12873.2695      0.1330
>      179    181   88.6    0.2977 4411.0838      0.1470
>      181    195   96.6    0.2575 963.1998      0.1530
>      195    197   87.4    0.1997 250.2422      0.1330
>      195    196   80.6    0.1807 246.3256      0.1230
>      181    182   83.5    0.6596 33817.6412      0.1530
>      182    183   90.9    0.3570 1629245.5886      0.1530
>      179    180  150.7    0.1744 806.4780      0.1000
>      177    178   86.5    0.1487 13025.8466      0.1230
>      170    171  123.7    0.1636 1099.0521      0.1530
>      172    174  112.9    0.1334 124.2084      0.1330
>      172    173  119.8    0.1234 122.9154      0.1230
>      174    176   41.3    0.1000  19.2568      0.1000
>      141    149   30.5    0.1530   0.1924      0.1530
>      149    151  125.2    0.1330  18.9674      0.1330
>      149    150   34.1    0.1230   0.1614      0.1230
>      151    153   35.8    0.1471  28.7745      0.1470
>      151    152   83.3    0.1000  18.9746      0.1000
>      166    167  115.5    0.1238 341.2685      0.1230
>      153    166  117.8    0.1538 365.5008      0.1530
>      153    154   37.0    0.1531  14.8979      0.1530
>      154    155   90.8    0.1530  15.6791      0.1530
>      155    158   33.4    0.1390   0.1782      0.1390
>      155    156   32.8    0.1390   0.1771      0.1390
>      168    170  141.4    0.1596 1274.6369      0.1470
>      168    169   93.7    0.1015 232.5375      0.1000
>
> Step 1, time 0.002 (ps)  LINCS WARNING
> relative constraint deviation after LINCS:
> rms 12958124.333813, max 292691795.227618 (between atoms 184 and 188)
> bonds that rotated more than 30 degrees:
>   atom 1 atom 2  angle  previous, current, constraint length
>      203    204   32.1    0.1470   0.1744      0.1470
>      201    202   74.0    0.1532   1.1957      0.1530
>      202    203  117.7    0.1530   0.3991      0.1530
>      208    210   59.2    0.1359   3.5580      0.1330
>      208    209   73.2    0.1256   1.9933      0.1230
>      210    212   74.8    0.1480   1.9178      0.1470
>      210    211   93.8    0.1007   1.5815      0.1000
>      177    179   94.9    0.2195 12873.2691      0.1330
>      177    178   86.5    0.1487 13025.8467      0.1230
>      170    177   81.9    0.1793 13127.8623      0.1530
>      170    171  123.7    0.1636 1099.0521      0.1530
>      172    174  112.9    0.1334 124.2084      0.1330
>      174    176   41.3    0.1000  19.2568      0.1000
>      172    173  119.8    0.1234 122.9154      0.1230
>      168    170  141.4    0.1596 1274.6369      0.1470
>      168    169   93.7    0.1015 232.5375      0.1000
>      166    167  115.5    0.1238 341.2681      0.1230
>      153    166  117.8    0.1538 365.5039      0.1530
>      153    154   37.0    0.1531  14.8978      0.1530
>      151    153   35.8    0.1471  28.7776      0.1470
>      179    181   88.6    0.2977 4411.0814      0.1470
>      179    180  150.7    0.1744 806.4798      0.1000
>      212    217  118.1    0.1531   1.2961      0.1530
>      212    213  109.4    0.1531   1.3254      0.1530
>      213    214   39.0    0.1530   0.2085      0.1530
>      155    156   32.8    0.1390   0.1771      0.1390
>      155    158   33.4    0.1390   0.1782      0.1390
>      154    155   90.8    0.1530  15.6794      0.1530
>      151    152   83.3    0.1000  18.9666      0.1000
>      149    151  125.2    0.1330  18.9811      0.1330
>     4555   4554   30.1    0.1054   0.0939      0.1000
>     4569   4556   74.8    0.0906   0.1937      0.1390
>      181    195   96.6    0.2575 963.1279      0.1530
>      181    182   83.5    0.6596 33817.6442      0.1530
>      182    183   90.9    0.3570 1629245.5155      0.1530
>      183    186   90.6    1.1049 1615814.4351      0.1390
>      183    184   90.0    0.9974 40335415.9560      0.1390
>      186    190   96.9    0.1988 560191.7122      0.1390
>      186    187   88.8    0.3696 201776.9576      0.1090
>      188    192   67.5    1.1955 1821775.8654      0.1390
>      188    189  101.2    0.3759 1696383.9645      0.1090
>      190    192   81.7    1.1212 1424433.0456      0.1390
>      190    191   87.4    0.3818 426096.7655      0.1090
>      195    197   87.4    0.1997 250.1707      0.1330
>      195    196   80.6    0.1807 246.3559      0.1230
>      197    199  115.6    0.1672  46.7731      0.1470
>      197    198   93.5    0.1195  71.3260      0.1000
>      199    208  110.1    0.1646  12.2018      0.1530
>      199    200  126.5    0.1592  13.4121      0.1530
>     4571   4569   57.6    0.0953   0.1778      0.1400
>     4570   4569   96.5    0.1846   0.0942      0.1230
>     4573   4571  129.0    0.1855 14090.0537      0.1480
>     4572   4571   57.4    0.1253   0.1613      0.1000
>      184    188   89.7    0.2396 40684159.6756      0.1390
>      184    185   90.6    0.4012 30909138.0053      0.1090
>     4581   4573  111.6    0.1449 80915.8503      0.1390
>     4574   4573   76.0    0.1584 14090.0686      0.1530
>     4575   4574   42.1    0.1584   0.2180      0.1530
>     4583   4581  115.9    0.1482 189006.2806      0.1400
>     4582   4581  101.5    0.1307 86465.6939      0.1230
>     4585   4583   96.2    0.1493 1521854.0321      0.1480
>     4584   4583  100.1    0.1012 212428.0383      0.1000
>      217    219   33.2    0.1331   0.1875      0.1330
>      217    218   39.2    0.1230   0.1766      0.1230
>      432    433   90.0    0.1090   4.9068      0.1090
>     4693   4691   33.2    0.1400   0.1794      0.1400
>     4695   4693  113.6    0.1390 48586.2542      0.1390
>     4694   4693   32.2    0.1230   0.1573      0.1230
>     4704   4702  109.2    0.1400 941999.6432      0.1400
>     4703   4702  107.8    0.1000 247420.2683      0.1000
>     4706   4704   97.5    0.1390 3171125.9217      0.1390
>     4705   4704  107.2    0.1230 927537.6196      0.1230
>     4707   4706   95.6    0.1480 2865230.8599      0.1480
>     4709   4707  106.5    0.1400 1358764.5608      0.1400
>     4708   4707  100.7    0.1000 1219377.5021      0.1000
>     4702   4695  101.5    0.1480 271922.1291      0.1480
>     4696   4695   99.4    0.1530 48586.2478      0.1530
>     4700   4696   35.0    0.1430   0.1795      0.1430
>     4697   4696   31.7    0.1530   0.1878      0.1530
>      192    193   87.7    0.1711 1385085.9069      0.1360
>      193    194  122.8    0.6012 463629.3169      0.1000
>     4589   4585   98.8    0.1400 1434753.0952      0.1390
>     4586   4585   99.5    0.1525 1727093.0923      0.1520
>     4587   4586   91.3    0.1781 11019687.9112      0.1780
>     4588   4587   90.9    0.1780 7508588.7244      0.1780
>     4706   4588   96.7    0.1520 7576848.4015      0.1520
>     4591   4589  115.3    0.1401 374617.1180      0.1400
>     4590   4589  104.7    0.1231 385431.1813      0.1230
>     4593   4591  120.6    0.1482 84232.5460      0.1480
>     4592   4591  104.8    0.1001 97469.7963      0.1000
>     4598   4593  119.3    0.1520 34449.1440      0.1520
>     4594   4593  132.0    0.1391 34449.1610      0.1390
>     4596   4594   37.3    0.1401   0.2053      0.1400
>     4595   4594   38.0    0.1231   0.1829      0.1230
>     4599   4598   37.9    0.1780   0.2347      0.1780
>     4717   4715   42.7    0.1400   0.2049      0.1400
>     4716   4715   44.0    0.1000   0.1533      0.1000
>     4711   4709  107.3    0.1390 242148.6477      0.1390
>     4710   4709  105.7    0.1230 267458.4883      0.1230
>     4715   4711  114.1    0.1480 100450.2642      0.1480
>     4712   4711  122.6    0.1530 100450.2539      0.1530
>     4714   4712   44.6    0.1530   0.2242      0.1530
>     4713   4712   43.2    0.1530   0.2226      0.1530
>
> step 1: Water molecule starting at atom 41146 can not be settled.
> Check for bad contacts and/or reduce the timestep if appropriate.
> Wrote pdb files with previous and current coordinates
> Wrote pdb files with previous and current coordinates
> Segmentation fault
>
> I have the following nvt.mdp
>
> title       = Protein-ligand complex NVT equilibration
> define      = -DPOSRES  ; position restrain the protein and ligand
> ; Run parameters
> integrator  = md        ; leap-frog integrator
> nsteps      = 150000     ; 2 * 150000 = 300 ps
> dt          = 0.002     ; 2 fs
> ; Output control
> nstxout     = 100       ; save coordinates every 0.2 ps
> nstvout     = 100       ; save velocities every 0.2 ps
> nstenergy   = 100       ; save energies every 0.2 ps
> nstlog      = 100       ; update log file every 0.2 ps
> energygrps  = Protein DRG
> ; Bond parameters
> continuation    = no            ; first dynamics run
> constraint_algorithm = lincs    ; holonomic constraints
> constraints     = all-bond    ; all bonds (even heavy atom-H bonds) constrained
> lincs_iter      = 1             ; accuracy of LINCS
> lincs_order     = 4             ; also related to accuracy
> ; Neighborsearching
> ns_type     = grid      ; search neighboring grid cells
> nstlist     = 5         ; 10 fs
> rlist       = 1.0       ; short-range neighborlist cutoff (in nm)
> rcoulomb    = 1.0      ; short-range electrostatic cutoff (in nm)
> rvdw        = 1.4       ; short-range van der Waals cutoff (in nm)
> ; Electrostatics
> coulombtype     = PME       ; Particle Mesh Ewald for long-range electrostatics
> pme_order       = 4         ; cubic interpolation
> fourierspacing  = 0.16      ; grid spacing for FFT
> ; Temperature coupling
> tcoupl      = V-rescale                     ; modified Berendsen thermostat
> tc-grps     = Protein_DRG Water_and_ions    ; two coupling groups -
> more accurate
> tau_t       = 0.1   0.1                     ; time constant, in ps
> ref_t       = 300   300                     ; reference temperature,
> one for each group, in K
> ; Pressure coupling
> pcoupl      = no        ; no pressure coupling in NVT
> ; Periodic boundary conditions
> pbc         = xyz       ; 3-D PBC
> ; Dispersion correction
> DispCorr    = EnerPres  ; account for cut-off vdW scheme
> ; Velocity generation
> gen_vel     = yes       ; assign velocities from Maxwell distribution
> gen_temp    = 300       ; temperature for Maxwell distribution
> gen_seed    = -1        ; generate a random seed
>
>
> If I do the constraints = none
>
> then i get the following warning-
> The bond in molecule-type Protein_chain_A between atoms 1 N and 2 H1 has
>    an estimated oscillational period of 1.0e-02 ps, which is less than 5
>    times the time step of 2.0e-03 ps.
>
> Should I change the dt=0.002 to dt=0.00001?

I doubt it will help.  If you want dt = 0.002, you must use constraints, so 
turning them off is not a wise idea.  The constraints are failing in the 
simulation, but that doesn't mean they are the cause of the problem.  They're 
just the first thing to fail due to insanely high forces.  Your run will 
undoubtedly fail without constraints eventually.

-Justin

-- 
==================================================

Justin A. Lemkul, Ph.D.
Ruth L. Kirschstein NRSA Postdoctoral Fellow

Department of Pharmaceutical Sciences
School of Pharmacy
Health Sciences Facility II, Room 601
University of Maryland, Baltimore
20 Penn St.
Baltimore, MD 21201

jalemkul at outerbanks.umaryland.edu | (410) 706-7441
http://mackerell.umaryland.edu/~jalemkul

==================================================


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