[gmx-users] total charge (qtot)

James Lord jjamesgreen110 at gmail.com
Wed May 13 15:06:18 CEST 2015


I can see that I have two chains but can I simply say the total charge is
-7 e?
Cheers
James

On Thu, May 14, 2015 at 1:04 AM, James Lord <jjamesgreen110 at gmail.com>
wrote:

> Dear gmx users,
> I am trying to repeat Justin's Lysozyme tutorial for 1HFX.pdb,
>
>
> https://drive.google.com/file/d/0B0YMTXH1gmQsUjVSd01ERXVpLTA/view?usp=sharing
>
> I would like to know the total charge of my system but I have two
> statement for that,after running
>
> pdb2gmx -f 1HFX.pdb -o 1HFX_processed.gro -water spce
>
>  one is saying -9e and 2e? I am a bit confuse can anyone tell me why it is
> like this? I also checked the topol.top and there is no "qtot"
>
>
> pdb2gmx -f 1HFX.pdb -o 1HFX_processed.gro -water spce
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>              of the License, or (at your option) any later version.
>
>                                :-)  pdb2gmx  (-:
>
> Option     Filename  Type         Description
> ------------------------------------------------------------
>   -f       1HFX.pdb  Input        Structure file: gro g96 pdb tpr etc.
>   -o 1HFX_processed.gro  Output       Structure file: gro g96 pdb etc.
>   -p      topol.top  Output       Topology file
>   -i      posre.itp  Output       Include file for topology
>   -n      clean.ndx  Output, Opt. Index file
>   -q      clean.pdb  Output, Opt. Structure file: gro g96 pdb etc.
>
> Option       Type   Value   Description
> ------------------------------------------------------
> -[no]h       bool   no      Print help info and quit
> -[no]version bool   no      Print version info and quit
> -nice        int    0       Set the nicelevel
> -chainsep    enum   id_or_ter  Condition in PDB files when a new chain
> should
>                             be started (adding termini): id_or_ter,
>                             id_and_ter, ter, id or interactive
> -merge       enum   no      Merge multiple chains into a single
>                             [moleculetype]: no, all or interactive
> -ff          string select  Force field, interactive by default. Use -h for
>                             information.
> -water       enum   spce    Water model to use: select, none, spc, spce,
>                             tip3p, tip4p or tip5p
> -[no]inter   bool   no      Set the next 8 options to interactive
> -[no]ss      bool   no      Interactive SS bridge selection
> -[no]ter     bool   no      Interactive termini selection, instead of
> charged
>                             (default)
> -[no]lys     bool   no      Interactive lysine selection, instead of
> charged
> -[no]arg     bool   no      Interactive arginine selection, instead of
> charged
> -[no]asp     bool   no      Interactive aspartic acid selection, instead of
>                             charged
> -[no]glu     bool   no      Interactive glutamic acid selection, instead of
>                             charged
> -[no]gln     bool   no      Interactive glutamine selection, instead of
>                             neutral
> -[no]his     bool   no      Interactive histidine selection, instead of
>                             checking H-bonds
> -angle       real   135     Minimum hydrogen-donor-acceptor angle for a
>                             H-bond (degrees)
> -dist        real   0.3     Maximum donor-acceptor distance for a H-bond
> (nm)
> -[no]una     bool   no      Select aromatic rings with united CH atoms on
>                             phenylalanine, tryptophane and tyrosine
> -[no]ignh    bool   no      Ignore hydrogen atoms that are in the
> coordinate
>                             file
> -[no]missing bool   no      Continue when atoms are missing, dangerous
> -[no]v       bool   no      Be slightly more verbose in messages
> -posrefc     real   1000    Force constant for position restraints
> -vsite       enum   none    Convert atoms to virtual sites: none, hydrogens
>                             or aromatics
> -[no]heavyh  bool   no      Make hydrogen atoms heavy
> -[no]deuterate bool no      Change the mass of hydrogens to 2 amu
> -[no]chargegrp bool yes     Use charge groups in the .rtp file
> -[no]cmap    bool   yes     Use cmap torsions (if enabled in the .rtp file)
> -[no]renum   bool   no      Renumber the residues consecutively in the
> output
> -[no]rtpres  bool   no      Use .rtp entry names as residue names
>
>
> Select the Force Field:
> From '/usr/local/gromacs/share/gromacs/top':
>  1: AMBER03 protein, nucleic AMBER94 (Duan et al., J. Comp. Chem. 24,
> 1999-2012, 2003)
>  2: AMBER94 force field (Cornell et al., JACS 117, 5179-5197, 1995)
>  3: AMBER96 protein, nucleic AMBER94 (Kollman et al., Acc. Chem. Res. 29,
> 461-469, 1996)
>  4: AMBER99 protein, nucleic AMBER94 (Wang et al., J. Comp. Chem. 21,
> 1049-1074, 2000)
>  5: AMBER99SB protein, nucleic AMBER94 (Hornak et al., Proteins 65,
> 712-725, 2006)
>  6: AMBER99SB-ILDN protein, nucleic AMBER94 (Lindorff-Larsen et al.,
> Proteins 78, 1950-58, 2010)
>  7: AMBERGS force field (Garcia & Sanbonmatsu, PNAS 99, 2782-2787, 2002)
>  8: CHARMM27 all-atom force field (with CMAP) - version 2.0
>  9: GROMOS96 43a1 force field
> 10: GROMOS96 43a2 force field (improved alkane dihedrals)
> 11: GROMOS96 45a3 force field (Schuler JCC 2001 22 1205)
> 12: GROMOS96 53a5 force field (JCC 2004 vol 25 pag 1656)
> 13: GROMOS96 53a6 force field (JCC 2004 vol 25 pag 1656)
> 14: GROMOS96 54a7 force field (Eur. Biophys. J. (2011), 40,, 843-856, DOI:
> 10.1007/s00249-011-0700-9)
> 15: OPLS-AA/L all-atom force field (2001 aminoacid dihedrals)
> 16: [DEPRECATED] Encad all-atom force field, using full solvent charges
> 17: [DEPRECATED] Encad all-atom force field, using scaled-down vacuum
> charges
> 18: [DEPRECATED] Gromacs force field (see manual)
> 19: [DEPRECATED] Gromacs force field with hydrogens for NMR
> 15
>
> Using the Oplsaa force field in directory oplsaa.ff
>
> Opening force field file
> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.r2b
> Reading 1HFX.pdb...
> WARNING: all CONECT records are ignored
> Read 'ALPHA-LACTALBUMIN', 1069 atoms
> Analyzing pdb file
> Splitting chemical chains based on TER records or chain id changing.
> WARNING: Chain identifier 'A' is used in two non-sequential blocks.
> They will be treated as separate chains unless you reorder your file.
> There are 2 chains and 1 blocks of water and 197 residues with 1069 atoms
>
>   chain  #res #atoms
>   1 'A'   123    995
>   2 'A'     1      1
>   3 ' '    73     73  (only water)
>
> All occupancies are one
> Opening force field file
> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/atomtypes.atp
> Atomtype 1
> Reading residue database... (oplsaa)
> Opening force field file
> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.rtp
> Residue 54
> Sorting it all out...
> Opening force field file
> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.hdb
> Opening force field file
> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.n.tdb
> Opening force field file
> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.c.tdb
>
> Back Off! I just backed up topol.top to ./#topol.top.2#
> Processing chain 1 'A' (995 atoms, 123 residues)
> Analysing hydrogen-bonding network for automated assignment of histidine
>  protonation. 180 donors and 196 acceptors were found.
> There are 262 hydrogen bonds
> Will use HISE for residue 10
> Will use HISD for residue 32
> Will use HISE for residue 47
> Will use HISE for residue 107
> Identified residue LYS1 as a starting terminus.
> Identified residue GLN123 as a ending terminus.
> 8 out of 8 lines of specbond.dat converted successfully
> Special Atom Distance matrix:
>                     CYS6   HIS10   CYS28   HIS32   HIS47   CYS61   CYS73
>                     SG48   NE277   SG225  NE2262  NE2377   SG497   SG587
>    HIS10   NE277   0.715
>    CYS28   SG225   1.522   1.948
>    HIS32  NE2262   1.791   2.287   0.484
>    HIS47  NE2377   3.051   3.232   2.060   1.880
>    CYS61   SG497   2.817   2.797   2.313   2.287   1.017
>    CYS73   SG587   2.748   2.608   2.233   2.350   1.390   0.757
>    CYS77   SG615   2.932   2.917   2.465   2.415   1.078   0.203   0.934
>    MET90   SD718   2.683   2.405   2.447   2.639   1.913   1.131   0.544
>    CYS91   SG725   2.575   2.458   2.088   2.198   1.330   0.672   0.201
>   HIS107  NE2860   3.163   3.372   1.773   1.726   1.369   2.067   1.912
>   CYS111   SG890   1.677   2.062   0.202   0.475   1.889   2.183   2.098
>   CYS120   SG971   0.203   0.608   1.553   1.867   3.125   2.877   2.754
>                    CYS77   MET90   CYS91  HIS107  CYS111
>                    SG615   SD718   SG725  NE2860   SG890
>    MET90   SD718   1.271
>    CYS91   SG725   0.860   0.592
>   HIS107  NE2860   2.219   2.366   1.903
>   CYS111   SG890   2.339   2.344   1.960   1.576
>   CYS120   SG971   3.001   2.665   2.589   3.175   1.707
> Linking CYS-6 SG-48 and CYS-120 SG-971...
> Linking CYS-28 SG-225 and CYS-111 SG-890...
> Linking CYS-61 SG-497 and CYS-77 SG-615...
> Linking CYS-73 SG-587 and CYS-91 SG-725...
> Start terminus LYS-1: NH3+
> End terminus GLN-123: COO-
> Checking for duplicate atoms....
> Generating any missing hydrogen atoms and/or adding termini.
> Now there are 123 residues with 1955 atoms
> Chain time...
>
> Back Off! I just backed up topol_Protein_chain_A.itp to
> ./#topol_Protein_chain_A.itp.2#
> Making bonds...
> Number of bonds was 1978, now 1978
> Generating angles, dihedrals and pairs...
> Before cleaning: 5220 pairs
> Before cleaning: 5265 dihedrals
> Keeping all generated dihedrals
> Making cmap torsions...There are 5265 dihedrals,  380 impropers, 3584
> angles
>           5187 pairs,     1978 bonds and     0 virtual sites
> Total mass 14206.088 a.m.u.
> Total charge -9.000 e
> Writing topology
>
> Back Off! I just backed up posre_Protein_chain_A.itp to
> ./#posre_Protein_chain_A.itp.2#
> Processing chain 2 'A' (1 atoms, 1 residues)
> Warning: Starting residue CA124 in chain not identified as Protein/RNA/DNA.
> Problem with chain definition, or missing terminal residues.
> This chain does not appear to contain a recognized chain molecule.
> If this is incorrect, you can edit residuetypes.dat to modify the behavior.
> 8 out of 8 lines of specbond.dat converted successfully
> Checking for duplicate atoms....
> Generating any missing hydrogen atoms and/or adding termini.
> Now there are 1 residues with 1 atoms
> Chain time...
>
> Back Off! I just backed up topol_Ion_chain_A2.itp to
> ./#topol_Ion_chain_A2.itp.2#
> Making bonds...
> No bonds
> Generating angles, dihedrals and pairs...
> Making cmap torsions...There are    0 dihedrals,    0 impropers,    0
> angles
>              0 pairs,        0 bonds and     0 virtual sites
> Total mass 40.080 a.m.u.
> Total charge 2.000 e
> Writing topology
>
> Back Off! I just backed up posre_Ion_chain_A2.itp to
> ./#posre_Ion_chain_A2.itp.2#
> Processing chain 3 (73 atoms, 73 residues)
> Problem with chain definition, or missing terminal residues.
> This chain does not appear to contain a recognized chain molecule.
> If this is incorrect, you can edit residuetypes.dat to modify the behavior.
> 8 out of 8 lines of specbond.dat converted successfully
> Checking for duplicate atoms....
> Generating any missing hydrogen atoms and/or adding termini.
> Now there are 73 residues with 219 atoms
> Making bonds...
> Number of bonds was 146, now 146
> Generating angles, dihedrals and pairs...
> Making cmap torsions...There are    0 dihedrals,    0 impropers,   73
> angles
>              0 pairs,      146 bonds and     0 virtual sites
> Total mass 1315.124 a.m.u.
> Total charge 0.000 e
> Including chain 1 in system: 1955 atoms 123 residues
> Including chain 2 in system: 1 atoms 1 residues
> Including chain 3 in system: 219 atoms 73 residues
> Now there are 2175 atoms and 197 residues
> Total mass in system 15561.292 a.m.u.
> Total charge in system -7.000 e
>
> Writing coordinate file...
>
> Back Off! I just backed up 1HFX_processed.gro to ./#1HFX_processed.gro.2#
>         --------- PLEASE NOTE ------------
> You have successfully generated a topology from: 1HFX.pdb.
> The Oplsaa force field and the spce water model are used.
>         --------- ETON ESAELP ------------
>
> Cheers
> James
>


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