[gmx-users] total charge (qtot)

James Lord jjamesgreen110 at gmail.com
Thu May 14 03:17:48 CEST 2015


ops silly one though, I meant just need to select solvent when asked right?

On Thu, May 14, 2015 at 1:13 PM, James Lord <jjamesgreen110 at gmail.com>
wrote:

> Thanks Justin,
>>
>> So Just adding +7 Na to the whole system should be good to go to next
>> step? or do I need to neutralize each chain separately? If yes how?
>
> Cheers
> James
>
> On Thu, May 14, 2015 at 1:05 AM, Justin Lemkul <jalemkul at vt.edu> wrote:
>
>>
>>
>> On 5/13/15 9:04 AM, James Lord wrote:
>>
>>> Dear gmx users,
>>> I am trying to repeat Justin's Lysozyme tutorial for 1HFX.pdb,
>>>
>>>
>>> https://drive.google.com/file/d/0B0YMTXH1gmQsUjVSd01ERXVpLTA/view?usp=sharing
>>>
>>> I would like to know the total charge of my system but I have two
>>> statement
>>> for that,after running
>>>
>>> pdb2gmx -f 1HFX.pdb -o 1HFX_processed.gro -water spce
>>>
>>>   one is saying -9e and 2e? I am a bit confuse can anyone tell me why it
>>> is
>>> like this? I also checked the topol.top and there is no "qtot"
>>>
>>>
>> You have multiple chains, each with a net charge.  The qtot value is, in
>> fact, printed to the topology, just in each chain's .itp file.
>>
>> -Justin
>>
>>
>>
>>> pdb2gmx -f 1HFX.pdb -o 1HFX_processed.gro -water spce
>>>                           :-)  G  R  O  M  A  C  S  (-:
>>>
>>>                   Good ROcking Metal Altar for Chronical Sinners
>>>
>>>                              :-)  VERSION 4.6.3  (-:
>>>
>>>          Contributions from Mark Abraham, Emile Apol, Rossen Apostolov,
>>>             Herman J.C. Berendsen, Aldert van Buuren, Pär Bjelkmar,
>>>       Rudi van Drunen, Anton Feenstra, Gerrit Groenhof, Christoph
>>> Junghans,
>>>          Peter Kasson, Carsten Kutzner, Per Larsson, Pieter Meulenhoff,
>>>             Teemu Murtola, Szilard Pall, Sander Pronk, Roland Schulz,
>>>                  Michael Shirts, Alfons Sijbers, Peter Tieleman,
>>>
>>>                 Berk Hess, David van der Spoel, and Erik Lindahl.
>>>
>>>         Copyright (c) 1991-2000, University of Groningen, The
>>> Netherlands.
>>>           Copyright (c) 2001-2012,2013, The GROMACS development team at
>>>          Uppsala University & The Royal Institute of Technology, Sweden.
>>>              check out http://www.gromacs.org for more information.
>>>
>>>           This program is free software; you can redistribute it and/or
>>>         modify it under the terms of the GNU Lesser General Public
>>> License
>>>          as published by the Free Software Foundation; either version 2.1
>>>               of the License, or (at your option) any later version.
>>>
>>>                                 :-)  pdb2gmx  (-:
>>>
>>> Option     Filename  Type         Description
>>> ------------------------------------------------------------
>>>    -f       1HFX.pdb  Input        Structure file: gro g96 pdb tpr etc.
>>>    -o 1HFX_processed.gro  Output       Structure file: gro g96 pdb etc.
>>>    -p      topol.top  Output       Topology file
>>>    -i      posre.itp  Output       Include file for topology
>>>    -n      clean.ndx  Output, Opt. Index file
>>>    -q      clean.pdb  Output, Opt. Structure file: gro g96 pdb etc.
>>>
>>> Option       Type   Value   Description
>>> ------------------------------------------------------
>>> -[no]h       bool   no      Print help info and quit
>>> -[no]version bool   no      Print version info and quit
>>> -nice        int    0       Set the nicelevel
>>> -chainsep    enum   id_or_ter  Condition in PDB files when a new chain
>>> should
>>>                              be started (adding termini): id_or_ter,
>>>                              id_and_ter, ter, id or interactive
>>> -merge       enum   no      Merge multiple chains into a single
>>>                              [moleculetype]: no, all or interactive
>>> -ff          string select  Force field, interactive by default. Use -h
>>> for
>>>                              information.
>>> -water       enum   spce    Water model to use: select, none, spc, spce,
>>>                              tip3p, tip4p or tip5p
>>> -[no]inter   bool   no      Set the next 8 options to interactive
>>> -[no]ss      bool   no      Interactive SS bridge selection
>>> -[no]ter     bool   no      Interactive termini selection, instead of
>>> charged
>>>                              (default)
>>> -[no]lys     bool   no      Interactive lysine selection, instead of
>>> charged
>>> -[no]arg     bool   no      Interactive arginine selection, instead of
>>> charged
>>> -[no]asp     bool   no      Interactive aspartic acid selection, instead
>>> of
>>>                              charged
>>> -[no]glu     bool   no      Interactive glutamic acid selection, instead
>>> of
>>>                              charged
>>> -[no]gln     bool   no      Interactive glutamine selection, instead of
>>>                              neutral
>>> -[no]his     bool   no      Interactive histidine selection, instead of
>>>                              checking H-bonds
>>> -angle       real   135     Minimum hydrogen-donor-acceptor angle for a
>>>                              H-bond (degrees)
>>> -dist        real   0.3     Maximum donor-acceptor distance for a H-bond
>>> (nm)
>>> -[no]una     bool   no      Select aromatic rings with united CH atoms on
>>>                              phenylalanine, tryptophane and tyrosine
>>> -[no]ignh    bool   no      Ignore hydrogen atoms that are in the
>>> coordinate
>>>                              file
>>> -[no]missing bool   no      Continue when atoms are missing, dangerous
>>> -[no]v       bool   no      Be slightly more verbose in messages
>>> -posrefc     real   1000    Force constant for position restraints
>>> -vsite       enum   none    Convert atoms to virtual sites: none,
>>> hydrogens
>>>                              or aromatics
>>> -[no]heavyh  bool   no      Make hydrogen atoms heavy
>>> -[no]deuterate bool no      Change the mass of hydrogens to 2 amu
>>> -[no]chargegrp bool yes     Use charge groups in the .rtp file
>>> -[no]cmap    bool   yes     Use cmap torsions (if enabled in the .rtp
>>> file)
>>> -[no]renum   bool   no      Renumber the residues consecutively in the
>>> output
>>> -[no]rtpres  bool   no      Use .rtp entry names as residue names
>>>
>>>
>>> Select the Force Field:
>>>  From '/usr/local/gromacs/share/gromacs/top':
>>>   1: AMBER03 protein, nucleic AMBER94 (Duan et al., J. Comp. Chem. 24,
>>> 1999-2012, 2003)
>>>   2: AMBER94 force field (Cornell et al., JACS 117, 5179-5197, 1995)
>>>   3: AMBER96 protein, nucleic AMBER94 (Kollman et al., Acc. Chem. Res.
>>> 29,
>>> 461-469, 1996)
>>>   4: AMBER99 protein, nucleic AMBER94 (Wang et al., J. Comp. Chem. 21,
>>> 1049-1074, 2000)
>>>   5: AMBER99SB protein, nucleic AMBER94 (Hornak et al., Proteins 65,
>>> 712-725, 2006)
>>>   6: AMBER99SB-ILDN protein, nucleic AMBER94 (Lindorff-Larsen et al.,
>>> Proteins 78, 1950-58, 2010)
>>>   7: AMBERGS force field (Garcia & Sanbonmatsu, PNAS 99, 2782-2787, 2002)
>>>   8: CHARMM27 all-atom force field (with CMAP) - version 2.0
>>>   9: GROMOS96 43a1 force field
>>> 10: GROMOS96 43a2 force field (improved alkane dihedrals)
>>> 11: GROMOS96 45a3 force field (Schuler JCC 2001 22 1205)
>>> 12: GROMOS96 53a5 force field (JCC 2004 vol 25 pag 1656)
>>> 13: GROMOS96 53a6 force field (JCC 2004 vol 25 pag 1656)
>>> 14: GROMOS96 54a7 force field (Eur. Biophys. J. (2011), 40,, 843-856,
>>> DOI:
>>> 10.1007/s00249-011-0700-9)
>>> 15: OPLS-AA/L all-atom force field (2001 aminoacid dihedrals)
>>> 16: [DEPRECATED] Encad all-atom force field, using full solvent charges
>>> 17: [DEPRECATED] Encad all-atom force field, using scaled-down vacuum
>>> charges
>>> 18: [DEPRECATED] Gromacs force field (see manual)
>>> 19: [DEPRECATED] Gromacs force field with hydrogens for NMR
>>> 15
>>>
>>> Using the Oplsaa force field in directory oplsaa.ff
>>>
>>> Opening force field file
>>> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.r2b
>>> Reading 1HFX.pdb...
>>> WARNING: all CONECT records are ignored
>>> Read 'ALPHA-LACTALBUMIN', 1069 atoms
>>> Analyzing pdb file
>>> Splitting chemical chains based on TER records or chain id changing.
>>> WARNING: Chain identifier 'A' is used in two non-sequential blocks.
>>> They will be treated as separate chains unless you reorder your file.
>>> There are 2 chains and 1 blocks of water and 197 residues with 1069 atoms
>>>
>>>    chain  #res #atoms
>>>    1 'A'   123    995
>>>    2 'A'     1      1
>>>    3 ' '    73     73  (only water)
>>>
>>> All occupancies are one
>>> Opening force field file
>>> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/atomtypes.atp
>>> Atomtype 1
>>> Reading residue database... (oplsaa)
>>> Opening force field file
>>> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.rtp
>>> Residue 54
>>> Sorting it all out...
>>> Opening force field file
>>> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.hdb
>>> Opening force field file
>>> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.n.tdb
>>> Opening force field file
>>> /usr/local/gromacs/share/gromacs/top/oplsaa.ff/aminoacids.c.tdb
>>>
>>> Back Off! I just backed up topol.top to ./#topol.top.2#
>>> Processing chain 1 'A' (995 atoms, 123 residues)
>>> Analysing hydrogen-bonding network for automated assignment of histidine
>>>   protonation. 180 donors and 196 acceptors were found.
>>> There are 262 hydrogen bonds
>>> Will use HISE for residue 10
>>> Will use HISD for residue 32
>>> Will use HISE for residue 47
>>> Will use HISE for residue 107
>>> Identified residue LYS1 as a starting terminus.
>>> Identified residue GLN123 as a ending terminus.
>>> 8 out of 8 lines of specbond.dat converted successfully
>>> Special Atom Distance matrix:
>>>                      CYS6   HIS10   CYS28   HIS32   HIS47   CYS61   CYS73
>>>                      SG48   NE277   SG225  NE2262  NE2377   SG497   SG587
>>>     HIS10   NE277   0.715
>>>     CYS28   SG225   1.522   1.948
>>>     HIS32  NE2262   1.791   2.287   0.484
>>>     HIS47  NE2377   3.051   3.232   2.060   1.880
>>>     CYS61   SG497   2.817   2.797   2.313   2.287   1.017
>>>     CYS73   SG587   2.748   2.608   2.233   2.350   1.390   0.757
>>>     CYS77   SG615   2.932   2.917   2.465   2.415   1.078   0.203   0.934
>>>     MET90   SD718   2.683   2.405   2.447   2.639   1.913   1.131   0.544
>>>     CYS91   SG725   2.575   2.458   2.088   2.198   1.330   0.672   0.201
>>>    HIS107  NE2860   3.163   3.372   1.773   1.726   1.369   2.067   1.912
>>>    CYS111   SG890   1.677   2.062   0.202   0.475   1.889   2.183   2.098
>>>    CYS120   SG971   0.203   0.608   1.553   1.867   3.125   2.877   2.754
>>>                     CYS77   MET90   CYS91  HIS107  CYS111
>>>                     SG615   SD718   SG725  NE2860   SG890
>>>     MET90   SD718   1.271
>>>     CYS91   SG725   0.860   0.592
>>>    HIS107  NE2860   2.219   2.366   1.903
>>>    CYS111   SG890   2.339   2.344   1.960   1.576
>>>    CYS120   SG971   3.001   2.665   2.589   3.175   1.707
>>> Linking CYS-6 SG-48 and CYS-120 SG-971...
>>> Linking CYS-28 SG-225 and CYS-111 SG-890...
>>> Linking CYS-61 SG-497 and CYS-77 SG-615...
>>> Linking CYS-73 SG-587 and CYS-91 SG-725...
>>> Start terminus LYS-1: NH3+
>>> End terminus GLN-123: COO-
>>> Checking for duplicate atoms....
>>> Generating any missing hydrogen atoms and/or adding termini.
>>> Now there are 123 residues with 1955 atoms
>>> Chain time...
>>>
>>> Back Off! I just backed up topol_Protein_chain_A.itp to
>>> ./#topol_Protein_chain_A.itp.2#
>>> Making bonds...
>>> Number of bonds was 1978, now 1978
>>> Generating angles, dihedrals and pairs...
>>> Before cleaning: 5220 pairs
>>> Before cleaning: 5265 dihedrals
>>> Keeping all generated dihedrals
>>> Making cmap torsions...There are 5265 dihedrals,  380 impropers, 3584
>>> angles
>>>            5187 pairs,     1978 bonds and     0 virtual sites
>>> Total mass 14206.088 a.m.u.
>>> Total charge -9.000 e
>>> Writing topology
>>>
>>> Back Off! I just backed up posre_Protein_chain_A.itp to
>>> ./#posre_Protein_chain_A.itp.2#
>>> Processing chain 2 'A' (1 atoms, 1 residues)
>>> Warning: Starting residue CA124 in chain not identified as
>>> Protein/RNA/DNA.
>>> Problem with chain definition, or missing terminal residues.
>>> This chain does not appear to contain a recognized chain molecule.
>>> If this is incorrect, you can edit residuetypes.dat to modify the
>>> behavior.
>>> 8 out of 8 lines of specbond.dat converted successfully
>>> Checking for duplicate atoms....
>>> Generating any missing hydrogen atoms and/or adding termini.
>>> Now there are 1 residues with 1 atoms
>>> Chain time...
>>>
>>> Back Off! I just backed up topol_Ion_chain_A2.itp to
>>> ./#topol_Ion_chain_A2.itp.2#
>>> Making bonds...
>>> No bonds
>>> Generating angles, dihedrals and pairs...
>>> Making cmap torsions...There are    0 dihedrals,    0 impropers,    0
>>> angles
>>>               0 pairs,        0 bonds and     0 virtual sites
>>> Total mass 40.080 a.m.u.
>>> Total charge 2.000 e
>>> Writing topology
>>>
>>> Back Off! I just backed up posre_Ion_chain_A2.itp to
>>> ./#posre_Ion_chain_A2.itp.2#
>>> Processing chain 3 (73 atoms, 73 residues)
>>> Problem with chain definition, or missing terminal residues.
>>> This chain does not appear to contain a recognized chain molecule.
>>> If this is incorrect, you can edit residuetypes.dat to modify the
>>> behavior.
>>> 8 out of 8 lines of specbond.dat converted successfully
>>> Checking for duplicate atoms....
>>> Generating any missing hydrogen atoms and/or adding termini.
>>> Now there are 73 residues with 219 atoms
>>> Making bonds...
>>> Number of bonds was 146, now 146
>>> Generating angles, dihedrals and pairs...
>>> Making cmap torsions...There are    0 dihedrals,    0 impropers,   73
>>> angles
>>>               0 pairs,      146 bonds and     0 virtual sites
>>> Total mass 1315.124 a.m.u.
>>> Total charge 0.000 e
>>> Including chain 1 in system: 1955 atoms 123 residues
>>> Including chain 2 in system: 1 atoms 1 residues
>>> Including chain 3 in system: 219 atoms 73 residues
>>> Now there are 2175 atoms and 197 residues
>>> Total mass in system 15561.292 a.m.u.
>>> Total charge in system -7.000 e
>>>
>>> Writing coordinate file...
>>>
>>> Back Off! I just backed up 1HFX_processed.gro to ./#1HFX_processed.gro.2#
>>>          --------- PLEASE NOTE ------------
>>> You have successfully generated a topology from: 1HFX.pdb.
>>> The Oplsaa force field and the spce water model are used.
>>>          --------- ETON ESAELP ------------
>>>
>>> Cheers
>>> James
>>>
>>>
>> --
>> ==================================================
>>
>> Justin A. Lemkul, Ph.D.
>> Ruth L. Kirschstein NRSA Postdoctoral Fellow
>>
>> Department of Pharmaceutical Sciences
>> School of Pharmacy
>> Health Sciences Facility II, Room 629
>> University of Maryland, Baltimore
>> 20 Penn St.
>> Baltimore, MD 21201
>>
>> jalemkul at outerbanks.umaryland.edu | (410) 706-7441
>> http://mackerell.umaryland.edu/~jalemkul
>>
>> ==================================================
>> --
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