[gmx-users] Simulated Tempering Issues

Alexander Yang ahy3nz at virginia.edu
Fri Jan 6 18:45:06 CET 2017


Dear Gromacs users,

I've been attempting simulated tempering (ST) in Gromacs to study gel-phase
bilayers (~15000 atoms), but I've been encountering some difficulties. I've
been following similar steps in the expanded ensemble tutorial on
alchemistry.org and adapting them for ST. The system I am studying is
already fairly well-equilibrated, so I don't imagine any huge movements in
the system.

I've picked very modest temperature values (305 K - 350 K with 2.5 K
spacing), yet I've been getting domain decomposition errors upon restarting
the simulation. I've done brief simulations (same MD parameters) on
clusters for 15 minutes and 30 minutes without crashing. When continuing
either simulation, the system crashes and throws the domain decomp error.
On the other hand, running these simulations indefinitely on the head node
does not exhibit crashes at the steps that have crashed for restarts after
15 minutes. I'm not sure if this is a coincidence with a ST move error, an
error with my MD parameters, or something with restarts. Could someone
advise? I've copied the error, last few lines of the log, and mdp below.

----Error----

Fatal error:

An atom moved too far between two domain decomposition steps

This usually means that your system is not well equilibrated

For more information and tips for troubleshooting, please check the GROMACS

website at http://www.gromacs.org/Documentation/Errors

------------

-----Log---
DD  step 3854999  vol min/aver 0.401  load imb.: force 11.2%  pme
mesh/force 2.059


           Step           Time         Lambda

        3855000     7710.00000        0.00000


   Energies (kJ/mol)

        G96Bond       G96Angle    Proper Dih.  Improper Dih.        LJ (SR)

    1.31304e+04    1.57687e+04    9.63926e+03    7.34404e+02   -9.18268e+03

  Disper. corr.   Coulomb (SR)   Coul. recip.      Potential    Kinetic En.

   -2.70660e+03   -2.50854e+05    1.12235e+03   -2.22348e+05    5.38027e+04

   Total Energy    Temperature Pres. DC (bar) Pressure (bar)

   -1.68545e+05    3.58572e+02   -1.70205e+02   -2.93216e+02


DD  step 3859999  vol min/aver 0.391  load imb.: force  7.7%  pme
mesh/force 2.344


           Step           Time         Lambda

        3860000     7720.00000        0.00000


             MC-lambda information

  Wang-Landau incrementor is:           1

  N  Temp.(K)    Count   G(in kT)  dG(in kT)

  1  305.000      193    0.00000  193.00000

  2  307.500        0  193.00000    0.00000

  3  310.000        0  193.00000    0.00000

  4  312.500        0  193.00000    0.00000

  5  315.000        0  193.00000    0.00000

  6  317.500        0  193.00000    0.00000

  7  320.000        0  193.00000    0.00000

  8  322.500        0  193.00000    0.00000

  9  325.000        0  193.00000  -35.00000

 10  327.500       35  158.00000  -96.00000

 11  330.000      131   62.00000  -95.00000

 12  332.500      226  -33.00000  -95.00000

 13  335.000      321 -128.00000  -95.00000

 14  337.500      416 -223.00000  -95.00000

 15  340.000      511 -318.00000  -95.00000

 16  342.500      606 -413.00000  -97.00000

 17  345.000      703 -510.00000  -93.00000

 18  347.500      796 -603.00000  -91.00000 <<

 19  350.000      887 -694.00000    0.00000


   Energies (kJ/mol)

        G96Bond       G96Angle    Proper Dih.  Improper Dih.        LJ (SR)

    1.24610e+04    1.60933e+04    9.86938e+03    7.51926e+02   -8.56113e+03

  Disper. corr.   Coulomb (SR)   Coul. recip.      Potential    Kinetic En.

   -2.69740e+03   -2.52430e+05    1.08555e+03   -2.23427e+05    5.48813e+04

   Total Energy    Temperature Pres. DC (bar) Pressure (bar)

   -1.68546e+05    3.65761e+02   -1.69051e+02    3.42231e+02


DD  step 3864999  vol min/aver 0.397  load imb.: force  9.8%  pme
mesh/force 1.822


           Step           Time         Lambda

        3865000     7730.00000        0.00000


   Energies (kJ/mol)

        G96Bond       G96Angle    Proper Dih.  Improper Dih.        LJ (SR)

    1.33244e+04    1.56493e+04    9.63355e+03    7.38294e+02   -7.52212e+03

  Disper. corr.   Coulomb (SR)   Coul. recip.      Potential    Kinetic En.

   -2.67952e+03   -2.52827e+05    1.16878e+03   -2.22514e+05    5.50394e+04

   Total Energy    Temperature Pres. DC (bar) Pressure (bar)

   -1.67475e+05    3.66815e+02   -1.66819e+02    5.74291e+02


+04

   Total Energy    Temperature Pres. DC (bar) Pressure (bar)

   -1.71349e+05    3.54322e+02   -1.63023e+02   -7.17865e+00

----


----MDP------
;title                       = Simulated Tempering Run

; Run parameters

integrator                  = md-vv

nsteps                      = 25000000     ; 50ns

dt                          = 0.002


; Output control

nstxout                     = 0             ; Don't save coordinates

nstvout                     = 0             ; Don't save velocities

nstenergy                   = 5000

nstlog                      = 5000

nstxtcout                   = 5000


;bond parameters

continuation                = yes

constraint_algorithm        = lincs ;lincs

constraints                 = hbonds

lincs_iter                  = 1

lincs_order                 = 4


; Neighbor searching

cutoff-scheme               = Verlet

ns_type                     = grid

nstlist                     = 10

rcoulomb                    = 1.4

rvdw                        = 1.4


;Electrostatics

coulombtype                 = PME

pme_order                   = 4

fourierspacing              = 0.16


; Temperature coupling

tcoupl                      = v-rescale ;v-rescale

tc-grps                     = non-water water

tau_t                       = 0.1   0.1

ref_t                       = 305   305


;Pressure coupling

pcoupl                      = berendsen;berendsen

pcoupltype                  = isotropic

tau_p                       = 1.0           ; ps

ref_p                       = 1.0           ; bar

compressibility             = 4.5e-5

refcoord_scaling            = com


;PBC

pbc                         = xyz


;Dispersion correction

DispCorr                    =EnerPres


;Velocity generation

gen_vel                     = no


;Simulated tempering

nstexpanded = 800

simulated-tempering = yes

sim-temp-low = 305

sim-temp-high = 355

simulated-tempering-scaling = linear

init_lambda_state = 0

temperature_lambdas = 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45
0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90

    0.95 1.00

lmc-stats = wang-landau

lmc-move = metropolized-gibbs

lmc-weights-equil = wl-delta

weight-equil-wl-delta = 0.001

wl-scale = 0.7

wl-ratio = 0.8

init-wl-delta = 1.0

wl-oneovert = yes
-------------

Thanks for the help,
Alex


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