[gmx-users] 1-4 Scaling Problem?

Chris Neale chris.neale at utoronto.ca
Mon May 26 17:28:43 CEST 2008


 >Dear Sir,
 >
 >I am sufferering from a dmpc-bilayer-area shrinking problem. The fact 
is the experimental area at 300K is 59.6A2,
 >where I am always getting 54A2 or 55A2 area. The dmpc_npat.pdb along 
with lipi.itp and dmpc.itp was taken from
 >the Tieleman's site, and I tried to modify these with half-epsilon 
double pairlist method to combine OPLS-BERGER.

Note added at the end: Some of your topology parameters are incorrect. 
That is likely the source of your problems. However, I left what I had 
already written prior to discovering those errors in case your problems 
persist...

Can you provide information about the standard deviation of the 
SA/lipid? Better yet, make a plot and post it on photobucket and then 
link that image to your next gromacs mailing list post.

Thank you for providing the information that experimental is 59.6A. What 
did Tieleman report? I have run his POPC with the .mdp options stated in 
the associated paper (LRLJ at 2.0nm) and found the area per lipid to 
shrink immediately. I concluded from that test that, for that one paper 
at least, either the methods section was not entirely correct, or the 
ambiguous way in which the type of pressure coupling was explained led 
me to do pressure coupling differently than they did (I used semiisotropic).

Therefore, I suggest that you first determine two things:
1) Look at the DMPC paper and figure out what area per lipid they report 
(and what the standard deviations are for that value). If they also 
report 55A from their simulations then

2) Since you have no protein, revert back prior to simple method of 
including lipid.itp via ffgmx and see what you get. I have tested POPC 
and DPPC and verified that I get the same values either with the above 
mentioned protocol or with the half-epsilon-double-pairlist method (for 
DPPC, see the .pdf that I posted wrt the method 
http://www.pomeslab.com/files/lipidCombinationRules.pdf). If you get the 
correct value via ffgmx and lipid.itp then you know that the problem 
lies with your topology. Otherwise, you can look to the .mdp files.

 >I am doing an initial minimisation (4500 steps with emtop 100) with 
flexible SPC and then turing on SETTLE and LINCS i am doing a 
pr-dynamics for 250ps and then MD run for 5ns. In the pr-dynamics, the 
area is around the original, but after starting MD, the area starts 
shrinking in 50ps only, and become continuous near 54A2. I know, 500ps 
is not sufficient for equilibration but the area shows no sign to again 
increase.

Even 5ns is not enough for equilibration. Run longer, it should not be 
very expensive to get >40ns. Check the plot at the bottom of that .pdf 
that I mentioned to see what the area/lipid fluctuations can look like.

 >
 >The pr.mdp is:
 >title               =  bilayer MD DMPC POSRES PURE
 >cpp                 =  /usr/bin/cpp
 >define              =  -DDMPCPOSRES
 >constraints         =  all-bonds
 >constraint_algorithm=  lincs  
 >lincs_order         =  4
 >lincs_warnangle     =  30
 >integrator          =  md
 >dt                  =  0.002    ; ps !
 >nsteps              =  125000    ; total 100 ps.
 >nstcomm             =  1
 >comm-mode           =  linear
 >nstxout             =  5000
 >nstvout             =  5000
 >nstfout             =  5000
 >nstenergy           =  1000
 >nstlist             =  5
 >ns_type             =  grid
 >rlist               =  0.9
 >rcoulomb            =  0.9
 >vdwtype             =  Cut-off
 >rvdw                =  1.4
 >fourierspacing      =  0.12
 >fourier_nx          =  0
 >fourier_ny          =  0
 >fourier_nz          =  0
 >coulombtype         =  PME
 >pme_order           =  4
 >ewald_rtol          =  1e-5
 >optimize_fft        =  yes
 >; Berendsen temperature coupling is on in two groups
 >Tcoupl              =  berendsen
 >tau_t               =  0.1           0.1
 >tc-grps             =  DMPC          sol
 >ref_t               =  300           300
 >; Pressure coupling is not on
 >Pcoupl              =  berendsen
 >tau_p               =  4.0           4.0
 >compressibility     =  4.5e-5        4.5e-5
 >ref_p               =  1.0           1.0
 >pcoupltype          =  semiisotropic
 >; Generate velocites is on at 300 K.
 >gen_vel             =  yes
 >gen_temp            =  300.0
 >gen_seed            =  173529
 >
 >the md.mdp file is:
 >
 >title               =  bilayer MD DMPC PURE
 >cpp                 =  /usr/bin/cpp
 >constraints         =  all-bonds
 >constraint_algorithm=  lincs  
 >lincs_order         =  4
 >lincs_warnangle     =  30
 >integrator          =  md
 >dt                  =  0.002    ; ps !
 >nsteps              =  2500000     ; total 100 ps.
 >nstcomm             =  1
 >comm-mode           =  linear
 >nstxout             =  5000
 >nstvout             =  5000
 >nstfout             =  5000
 >nstenergy           =  1000
 >nstlist             =  5
 >ns_type             =  grid
 >rlist               =  0.9
 >rcoulomb            =  0.9
 >vdwtype             =  Cut-off
 >rvdw                =  1.4
 >fourierspacing      =  0.12
 >fourier_nx          =  0
 >fourier_ny          =  0
 >fourier_nz          =  0
 >coulombtype         =  PME
 >pme_order           =  4
 >ewald_rtol          =  1e-5
 >optimize_fft        =  yes
 >; Berendsen temperature coupling is on in two groups
 >Tcoupl              =  berendsen
 >tau_t               =  0.1           0.1
 >tc-grps             =  DMPC          sol
 >ref_t               =  300           300
 >; Pressure coupling is not on
 >Pcoupl              =  berendsen
 >tau_p               =  4.0           4.0
 >compressibility     =  4.5e-5        4.5e-5
 >ref_p               =  1.0           1.0
 >pcoupltype          =  semiisotropic
 >; Generate velocites is on at 300 K.
 >gen_vel             =  yes
 >gen_temp            =  300.0
 >gen_seed            =  173529


I seriously hope that it doesn't matter, but I use nstlist = 10. You 
could try that just to see if the difference is there, and remember that 
if it is, this would make my simulations incorrect and yours correct.


 >
 >
 >the ffoplsaamd.itp is:
 >#define _FF_OPLS
 >#define _FF_OPLSAA
 >
 >; This force field uses a format that requires Gromacs 3.1.4 or later.
 >;
 >; References for the OPLS-AA force field:
 >;
 >; W. L. Jorgensen, D. S. Maxwell, and J. Tirado-Rives,
 >; J. Am. Chem. Soc. 118, 11225-11236 (1996).
 >; W. L. Jorgensen and N. A. McDonald, Theochem 424, 145-155 (1998).
 >; W. L. Jorgensen and N. A. McDonald, J. Phys. Chem. B 102, 8049-8059 
(1998).
 >; R. C. Rizzo and W. L. Jorgensen, J. Am. Chem. Soc. 121, 4827-4836 
(1999).
 >; M. L. Price, D. Ostrovsky, and W. L. Jorgensen, J. Comp. Chem. (2001).
 >; E. K. Watkins and W. L. Jorgensen, J. Phys. Chem. A 105, 4118-4125 
(2001)..
 >; G. A. Kaminski, R.A. Friesner, J.Tirado-Rives and W.L. Jorgensen, J. 
Phys.. Chem. B 105, 6474 (2001).
 >;
 >
 >[ defaults ]
 >; nbfunc       comb-rule       gen-pairs       fudgeLJ fudgeQQ
 >1              3               yes             0.5     0.5
 >
 >#include "ffoplsaanbmd.itp"
 >#include "ffoplsaabon.itp"
 >
 >the ffoplsaanbmd.itp is:
 >
 >[ atomtypes ]
 >; full atom descriptions are available in ffoplsaa.atp
 >; name  bond_type    mass    charge   ptype          sigma      epsilon
 >   LO   LO   1        15.9994      0.000       A    0.296      
0.87721   ;carbonyl O, OPLS
 >  LOM   LOM  1        15.9994      0.000       A    0.296      
0.87721   ;carboxyl O, OPLS
 >  LNL   LNL  1        14.0067      0.000       A    0.325      
0.7107   ;Nitrogen, OPLS
 >   LC   LC   1        12.0110      0.000       A    0.37499    
0.43967   ;Carbonyl C, OPLS
 >  LH1   LH1  1        13.0190      0.000       A    0.38002    
0.33451   ;CH1, OPLS
 >  LH2   LH2  1        14.0270      0.000       A    0.3905     
0.49353    ;CH2, OPLS
 >   LP   LP   1        30.9738      0.000       A    0.37400    
0.83653   ;phosphor, OPLS
 >  LOS   LOS  1        15.9994      0.000       A    0.29285    
1.0158    ;ester oxygen, OPLS
 >  LP2   LP2  1        14.0270      0.000       A    0.29999    
0.87809   ;RB CH2, Bergers LJ
 >  LP3   LP3  1        15.0350      0.000       A    0.396      
0.568937  ;RB CH3, Bergers LJ
 >  LC3   LC3  1        15.0350      0.000       A    0.39601    
0.67601   ;CH3, OPLS
 >  LC2   LC2  1        14.0270      0.000       A    0.3798     
0.49419   ;CH2, OPLS


Aha! Some of the above values are incorrect. For example, LC3 should 
read 0.3960142 and 0.606494
where you have 0.39601    0.67601.  The trailing decimals are probably 
not essential, but a difference
of >10% in the value of epsilon is sure to cause you headaches.

You also have incorrect values above for LOS and LP2, and perhaps others 
but I stopped checking at this
point. Strangely, you have the correct LO-LC3 and LC3-LC3 values in the 
[pairtypes] section below. I suggest that
you entirely remake this file and be very sure that you have done it 
correctly.

Chris.

 > .......................OPLS lines................................
 >
 >[ pairtypes ]
 >  ; i    j    func   sigma       epsilon
 >   LO    LO     1 0.29604      0.05482
 >   LO   LOM     1 0.29604      0.05482    
 >   LO  opls_113 1 0.30632      0.04733    
 >   LO   LNL     1 0.31018      0.04938    
 >   LO    LC     1 0.33319      0.0388    
 >   LO   LH1     1 0.33542      0.03383    
 >   LO   LH2     1 0.34001      0.04111    
 >   LO    LP     1 0.33275      0.05353    
 >   LO   LOS     1 0.29799      0.0549     
 >   LO   LP2     1 0.34237      0.03614    
 >   LO   LP3     1 0.34239      0.04414    
 >   LO   LC3     1 0.34238      0.04559    
 >   LO   LC2     1 0.33539      0.04115    
 >  LOM   LOM     1 0.29604      0.05482    
 >  LOM  opls_113 1 0.30632      0.04733    
 >  LOM   LNL     1 0.31018      0.04938    
 >  LOM    LC     1 0.33319      0.0388    
 >  LOM   LH1     1 0.33542      0.03383    
 >  LOM   LH2     1 0.34001      0.04111    
 >  LOM    LP     1 0.33275      0.05353    
 >  LOM   LOS     1 0.29799      0.0549     
 >  LOM   LP2     1 0.34237      0.03614    
 >  LOM   LP3     1 0.34239      0.04414    
 >  LOM   LC3     1 0.34238      0.04559    
 >  LOM   LC2     1 0.33539      0.04115    
 >opls_113 LNL     1 0.32095      0.04262    
 >opls_113 LC     1 0.34478      0.03347    
 >opls_113 LH1     1 0.34708      0.02921    
 >opls_113 LH2     1 0.35181      0.0355     
 >opls_113 LP     1 0.3443       0.04621    
 >opls_113 LOS     1 0.30836      0.04737    
 >opls_113 LP2     1 0.35427      0.0312     
 >opls_113 LP3     1 0.35427      0.03812    
 >opls_113 LC3     1 0.35428      0.03936    
 >opls_113 LC2     1 0.34705      0.03551    
 >  LNL    LNL     1 0.325        0.04446    
 >  LNL    LC     1 0.34912      0.03492    
 >  LNL   LH1     1 0.35145      0.03047    
 >  LNL   LH2     1 0.35625      0.03703   
 >  LNL    LP     1 0.34864      0.04822     
 >  LNL   LOS     1 0.31224      0.04944    
 >  LNL   LP2     1 0.35875      0.03254    
 >  LNL   LP3     1 0.35877      0.03975    
 >  LNL   LC3     1 0.35875      0.04106    
 >  LNL   LC2     1 0.35139      0.03707    
 >   LC    LC     1 0.37504      0.2743     
 >   LC   LH1     1 0.37751      0.02395    
 >   LC   LH2     1 0.3827       0.02908    
 >   LC    LP     1 0.37452      0.03787    
 >   LC   LOS     1 0.33542      0.03882    
 >   LC   LP2     1 0.38535      0.25565    
 >   LC   LP3     1 0.38539      0.03122    
 >   LC   LC3     1 0.38537      0.03225    
 >   LC   LC2     1 0.37751      0.02909    
 >  LH1   LH1     1 0.38004      0.02089    
 >  LH1   LH2     1 0.38525      0.02538     
 >  LH1    LP     1 0.37701      0.03305    
 >  LH1   LOS     1 0.33765      0.03388    
 >  LH1   LP2     1 0.38793      0.0223    
 >  LH1   LP3     1 0.38793      0.02724     
 >  LH1   LC3     1 0.38794      0.02814    
 >  LH1   LC2     1 0.38003      0.02539    
 >  LH2   LH2     1 0.39054      0.03082    
 >  LH2    LP     1 0.38218      0.04016    
 >  LH2   LOS     1 0.34227      0.04115    
 >  LH2   LP2     1 0.39324      0.0271     
 >  LH2   LP3     1 0.39328      0.03309    
 >  LH2   LC3     1 0.39324      0.03421    
 >  LH2   LC2     1 0.38523      0.03085    
 >   LP    LP     1 0.37399      0.0523    
 >   LP   LOS     1 0.33496      0.05359     
 >   LP   LP2     1 0.38483      0.03529    
 >   LP   LP3     1 0.38489      0.04306    
 >   LP   LC3     1 0.38487      0.04451    
 >   LP   LC2     1 0.37699      0.04017    
 >  LOS   LOS     1 0.29998      0.05495    
 >  LOS   LP2     1 0.34464      0.36185    
 >  LOS   LP3     1 0.34468      0.04419    
 >  LOS   LC3     1 0.34466      0.04564    
 >  LOS   LC2     1 0.33762      0.04118    
 >  LP2   LP2     1 0.39596      0.02382    
 >  LP2   LP3     1 0.396        0.02909    
 >  LP2   LC3     1 0.39599      0.03005    
 >  LP2   LC2     1 0.38789      0.02712    
 >  LP3   LP3     1 0.39601      0.03556    
 >  LP3   LC3     1 0.396        0.03673    
 >  LP3   LC2     1 0.38792      0.03313    
 >  LC3   LC3     1 0.39599      0.03793    
 >  LC3   LC2     1 0.38791      0.03422    
 >  LC2   LC2     1 0.37998      0.03088    
 >                                                                               
 
 >[ dihedraltypes ]
 >LP2 LP2  3   9.2789   12.156  -13.120 -3.0597 26.240 -31.495
 >LH2 LH2  3   9.2789   12.156  -13.120 -3.0597 26.240 -31.495
 >
 >the dmpcopls.itp is:
 >
 >[ moleculetype ]
 >
 >;   name  nrexcl
 >  DMPC       3
 >
 >[ atoms ]
 >;     id   atype   resnr resname   aname    cgnr  charge    mass
 >       1     LC3       1   DMPC      CN1       0  0.4000 15.0350
 >       2     LC3       1   DMPC      CN2       0  0.4000 15.0350
 >       3     LC3       1   DMPC      CN3       0  0.4000 15.0350
 >       4     LNL       1   DMPC      NTM       0 -0.5000 14.0067
 >       5     LH2       1   DMPC       CA       0  0.3000 14.0270
 >       6     LC2       1   DMPC       CB       1  0.4000 14.0270
 >       7     LOS       1   DMPC       OA       1 -0.8000 15.9994
 >       8      LP       1   DMPC        P       1  1.7000 30.9738
 >       9     LOM       1   DMPC       OB       1 -0.8000 15.9994
 >      10     LOM       1   DMPC       OC       1 -0.8000 15.9994
 >      11     LOS       1   DMPC       OD       1 -0.7000 15.9994
 >      12     LC2       1   DMPC       CC       2  0.4000 14.0270
 >      13     LH1       1   DMPC       CD       2  0.3000 13.0190
 >      14     LOS       1   DMPC       OE       2 -0.7000 15.9994
 >      15      LC       1   DMPC      C2A       2  0.7000 12.0110
 >      16      LO       1   DMPC       OF       2 -0.7000 15.9994
 >      17     LP2       1   DMPC      C2B       3  0.0000 14.0270
 >      18     LP2       1   DMPC      C2C       4  0.0000 14.0270
 >      19     LP2       1   DMPC      C2D       5  0.0000 14.0270
 >      20     LP2       1   DMPC      C2E       6  0.0000 14.0270
 >      21     LP2       1   DMPC      C2F       7  0.0000 14.0270
 >      22     LP2       1   DMPC      C2G       8  0.0000 14.0270
 >      23     LP2       1   DMPC      C2H       9  0.0000 14.0270
 >      24     LP2       1   DMPC      C2I      10  0.0000 14.0270
 >      25     LP2       1   DMPC      C2J      11  0.0000 14.0270
 >      26     LP2       1   DMPC      C2K      12  0.0000 14.0270
 >      27     LP2       1   DMPC      C2L      13  0.0000 14.0270
 >      28     LP2       1   DMPC      C2M      14  0.0000 14.0270
 >      29     LP3       1   DMPC      C2N      15  0.0000 15.0350
 >      30     LC2       1   DMPC       CE      18  0.5000 14.0270
 >      31     LOS       1   DMPC       OG      18 -0.7000 15.9994
 >      32      LC       1   DMPC      C1A      18  0.8000 12.0110
 >      33      LO       1   DMPC       OH      18 -0.6000 15.9994
 >      34     LP2       1   DMPC      C1B      19  0.0000 14.0270
 >      35     LP2       1   DMPC      C1C      20  0.0000 14.0270
 >      36     LP2       1   DMPC      C1D      21  0.0000 14.0270
 >      37     LP2       1   DMPC      C1E      22  0.0000 14.0270
 >      38     LP2       1   DMPC      C1F      23  0.0000 14.0270
 >      39     LP2       1   DMPC      C1G      24  0.0000 14.0270
 >      40     LP2       1   DMPC      C1H      25  0.0000 14.0270
 >      41     LP2       1   DMPC      C1I      26  0.0000 14.0270
 >      42     LP2       1   DMPC      C1J      27  0.0000 14.0270
 >      43     LP2       1   DMPC      C1K      28  0.0000 14.0270
 >      44     LP2       1   DMPC      C1L      29  0.0000 14.0270
 >      45     LP2       1   DMPC      C1M      30  0.0000 14.0270
 >      46     LP3       1   DMPC      C1N      31  0.0000 15.0350
 >
 >[ bonds ]
 >;     ai      aj    func          b0          cb
 >       1       4       1 0.14700E+00 0.37660E+06
 >       2       4       1 0.14700E+00 0.37660E+06
 >       3       4       1 0.14700E+00 0.37660E+06
 >       4       5       1 0.14700E+00 0.37660E+06
 >       5       6       1 0.15300E+00 0.33470E+06
 >       6       7       1 0.14300E+00 0.33470E+06
 >       7       8       1 0.16100E+00 0.25100E+06
 >       8       9       1 0.14800E+00 0.33470E+06
 >       8      10       1 0.14800E+00 0.33470E+06
 >       8      11       1 0.16100E+00 0.25100E+06
 >      11      12       1 0.14300E+00 0.33470E+06
 >      12      13       1 0.15300E+00 0.33470E+06
 >      13      14       1 0.14300E+00 0.33470E+06
 >      14      15       1 0.13600E+00 0.37660E+06
 >      15      16       1 0.12300E+00 0.50210E+06
 >      15      17       1 0.15300E+00 0.33470E+06
 >      17      18       1 0.15300E+00 0.33470E+06
 >      18      19       1 0.15300E+00 0.33470E+06
 >      19      20       1 0.15300E+00 0.33470E+06
 >      20      21       1 0.15300E+00 0.33470E+06
 >      21      22       1 0.15300E+00 0.33470E+06
 >      22      23       1 0.15300E+00 0.33470E+06
 >      23      24       1 0.15300E+00 0.33470E+06
 >      24      25       1 0.15300E+00 0.33470E+06
 >      25      26       1 0.15300E+00 0.33470E+06
 >      26      27       1 0.15300E+00 0.33470E+06
 >      27      28       1 0.15300E+00 0.33470E+06
 >      28      29       1 0.15300E+00 0.33470E+06
 >      13      30       1 0.15300E+00 0.33470E+06
 >      30      31       1 0.14300E+00 0.33470E+06
 >      31      32       1 0.13600E+00 0.37660E+06
 >      32      33       1 0.12300E+00 0.50210E+06
 >      32      34       1 0.15300E+00 0.33470E+06
 >      34      35       1 0.15300E+00 0.33470E+06
 >      35      36       1 0.15300E+00 0.33470E+06
 >      36      37       1 0.15300E+00 0.33470E+06
 >      37      38       1 0.15300E+00 0.33470E+06
 >      38      39       1 0.15300E+00 0.33470E+06
 >      39      40       1 0.15300E+00 0.33470E+06
 >      40      41       1 0.15300E+00 0.33470E+06
 >      41      42       1 0.15300E+00 0.33470E+06
 >      42      43       1 0.15300E+00 0.33470E+06
 >      43      44       1 0.15300E+00 0.33470E+06
 >      44      45       1 0.15300E+00 0.33470E+06
 >      45      46       1 0.15300E+00 0.33470E+06
 >
 >[ pairs ]
 >;Here is the first copy
 >      ai      aj    func          c6         c12
 >       1       6       1
 >       2       6       1
 >       3       6       1
 >       4       7       1
 >       5       8       1
 >       6       9       1
 >       6      10       1
 >       6      11       1
 >       7      12       1
 >       8      13       1
 >       9      12       1
 >      10      12       1
 >      11      14       1
 >      11      30       1
 >      12      15       1
 >      12      31       1
 >      13      16       1
 >      13      17       1
 >      13      32       1
 >      14      18       1
 >      14      31       1
 >      15      19       1
 >      15      30       1
 >      16      18       1
 >      30      33       1
 >      30      34       1
 >      31      35       1
 >      32      36       1
 >      33      35       1
 >; Here is the second copy. Only use this with the modified LJ-14 
epsilon values
 >       1       6       1
 >       2       6       1
 >       3       6       1
 >       4       7       1
 >       5       8       1
 >       6       9       1
 >       6      10       1
 >       6      11       1
 >       7      12       1
 >       8      13       1
 >       9      12       1
 >      10      12       1
 >      11      14       1
 >      11      30       1
 >      12      15       1
 >      12      31       1
 >      13      16       1
 >      13      17       1
 >      13      32       1
 >      14      18       1
 >      14      31       1
 >      15      19       1
 >      15      30       1
 >      16      18       1
 >      30      33       1
 >      30      34       1
 >      31      35       1
 >      32      36       1
 >      33      35       1
 >
 >[ angles ]
 >;     ai      aj      ak    func          t0          ct
 >       1       4       2       1 0.10950E+03 0.46020E+03
 >       1       4       3       1 0.10950E+03 0.46020E+03
 >       1       4       5       1 0.10950E+03 0.46020E+03
 >       2       4       3       1 0.10950E+03 0.46020E+03
 >       2       4       5       1 0.10950E+03 0.46020E+03
 >       3       4       5       1 0.10950E+03 0.46020E+03
 >       4       5       6       1 0.10950E+03 0.46020E+03
 >       5       6       7       1 0.10950E+03 0.46020E+03
 >       6       7       8       1 0.12000E+03 0.39750E+03
 >       7       8       9       1 0.10950E+03 0.39750E+03
 >       7       8      10       1 0.10950E+03 0.39750E+03
 >       7       8      11       1 0.10300E+03 0.39750E+03
 >       9       8      10       1 0.12000E+03 0.58580E+03
 >       9       8      11       1 0.10950E+03 0.39750E+03
 >      10       8      11       1 0.10950E+03 0.39750E+03
 >       8      11      12       1 0.12000E+03 0.39750E+03
 >      11      12      13       1 0.11100E+03 0.46020E+03
 >      12      13      14       1 0.10950E+03 0.46020E+03
 >      12      13      30       1 0.10950E+03 0.46020E+03
 >      14      13      30       1 0.10950E+03 0.46020E+03
 >      13      14      15       1 0.12000E+03 0.41840E+03
 >      14      15      16       1 0.12400E+03 0.50210E+03
 >      14      15      17       1 0.11500E+03 0.50210E+03
 >      16      15      17       1 0.12100E+03 0.50210E+03
 >      15      17      18       1 0.11100E+03 0.46020E+03
 >      17      18      19       1 0.11100E+03 0.46020E+03
 >      18      19      20       1 0.11100E+03 0.46020E+03
 >      19      20      21       1 0.11100E+03 0.46020E+03
 >      20      21      22       1 0.11100E+03 0.46020E+03
 >      21      22      23       1 0.11100E+03 0.46020E+03
 >      22      23      24       1 0.11100E+03 0.46020E+03
 >      23      24      25       1 0.11100E+03 0.46020E+03
 >      24      25      26       1 0.11100E+03 0.46020E+03
 >      25      26      27       1 0.11100E+03 0.46020E+03
 >      26      27      28       1 0.11100E+03 0.46020E+03
 >      27      28      29       1 0.11100E+03 0.46020E+03
 >      13      30      31       1 0.11100E+03 0.46020E+03
 >      30      31      32       1 0.12000E+03 0.41840E+03
 >      31      32      33       1 0.12400E+03 0.50210E+03
 >      31      32      34       1 0.11500E+03 0.50210E+03
 >      33      32      34       1 0.12100E+03 0.50210E+03
 >      32      34      35       1 0.11100E+03 0.46020E+03
 >      34      35      36       1 0.11100E+03 0.46020E+03
 >      35      36      37       1 0.11100E+03 0.46020E+03
 >      36      37      38       1 0.11100E+03 0.46020E+03
 >      37      38      39       1 0.11100E+03 0.46020E+03
 >      38      39      40       1 0.11100E+03 0.46020E+03
 >      39      40      41       1 0.11100E+03 0.46020E+03
 >      40      41      42       1 0.11100E+03 0.46020E+03
 >      41      42      43       1 0.11100E+03 0.46020E+03
 >      42      43      44       1 0.11100E+03 0.46020E+03
 >      43      44      45       1 0.11100E+03 0.46020E+03
 >      44      45      46       1 0.11100E+03 0.46020E+03
 >
 >[ dihedrals ]
 >; These are the improper dihedrals
 >;     ai      aj      ak      al    func          q0          cq
 >      13      14      30      12       2 0.35264E+02 0.33470E+03
 >      15      14      17      16       2 0.00000E+00 0.16740E+03
 >      32      31      34      33       2 0.00000E+00 0.16740E+03
 >
 >[ dihedrals ]
 >; These are the proper dihedrals
 >;     ai      aj      ak      al    func        phi0        cphi    mult
 >       1       4       5       6       1 0.00000E+00 0.37656E+01       3
 >       4       5       6       7       1 0.00000E+00 0.58576E+01       3
 >       5       6       7       8       1 0.00000E+00 0.37656E+01       3
 >       6       7       8      11       1 0.00000E+00 0.10460E+01       3
 >       7       8      11      12       1 0.00000E+00 0.10460E+01       3
 >       8      11      12      13       1 0.00000E+00 0.37656E+01       3
 >      11      12      13      14       1 0.00000E+00 0.20920E+01       2
 >      12      13      14      15       1 0.00000E+00 0.37656E+01       3
 >      13      14      15      17       1 0.18000E+03 0.16736E+02       2
 >      14      15      17      18       1 0.00000E+00 0.41840E+00       6
 >      15      17      18      19       1 0.00000E+00 0.58576E+01       3
 >      17      18      19      20       3
 >      18      19      20      21       3
 >      19      20      21      22       3
 >      20      21      22      23       3
 >      21      22      23      24       3
 >      22      23      24      25       3
 >      23      24      25      26       3
 >      24      25      26      27       3
 >      25      26      27      28       3
 >      26      27      28      29       3
 >      14      13      30      31       1 0.00000E+00 0.20920E+01       2
 >      13      30      31      32       1 0.00000E+00 0.37656E+01       3
 >      30      31      32      34       1 0.18000E+03 0.16736E+02       2
 >      31      32      34      35       1 0.00000E+00 0.41840E+00       6
 >      32      34      35      36       1 0.00000E+00 0.58576E+01       3
 >      34      35      36      37       3
 >      35      36      37      38       3
 >      36      37      38      39       3
 >      37      38      39      40       3
 >      38      39      40      41       3
 >      39      40      41      42       3
 >      40      41      42      43       3
 >      41      42      43      44       3
 >      42      43      44      45       3
 >      43      44      45      46       3
 >
 >#ifdef DMPC_POSRES
 >; position restraints for DMPC
 >[ position_restraints ]
 >; atom  type      fx      fy      fz
 >     1     1   1000.0  1000.0  1000.0
 >     2     1   1000.0  1000.0  1000.0
 >     3     1   1000.0  1000.0  1000.0
 >     4     1   1000.0  1000.0  1000.0
 >     5     1   1000.0  1000.0  1000.0
 >     6     1   1000.0  1000.0  1000.0
 >     7     1   1000.0  1000.0  1000.0
 >     8     1   1000.0  1000.0  1000.0
 >     9     1   1000.0  1000.0  1000.0
 >    10     1   1000.0  1000.0  1000.0
 >    11     1   1000.0  1000.0  1000.0
 >    12     1   1000.0  1000.0  1000.0
 >    13     1   1000.0  1000.0  1000.0
 >    14     1   1000.0  1000.0  1000.0
 >    15     1   1000.0  1000.0  1000.0
 >    16     1   1000.0  1000.0  1000.0
 >    17     1   1000.0  1000.0  1000.0
 >    18     1   1000.0  1000.0  1000.0
 >    19     1   1000.0  1000.0  1000.0
 >    20     1   1000.0  1000.0  1000.0
 >    21     1   1000.0  1000.0  1000.0
 >    22     1   1000.0  1000.0  1000.0
 >    23     1   1000.0  1000.0  1000.0
 >    24     1   1000.0  1000.0  1000.0
 >    25     1   1000.0  1000.0  1000.0
 >    26     1   1000.0  1000.0  1000.0
 >    27     1   1000.0  1000.0  1000.0
 >    28     1   1000.0  1000.0  1000.0
 >    29     1   1000.0  1000.0  1000.0
 >    30     1   1000.0  1000.0  1000.0
 >    31     1   1000.0  1000.0  1000.0
 >    32     1   1000.0  1000.0  1000.0
 >    33     1   1000.0  1000.0  1000.0
 >    34     1   1000.0  1000.0  1000.0
 >    35     1   1000.0  1000.0  1000.0
 >    36     1   1000.0  1000.0  1000.0
 >    37     1   1000.0  1000.0  1000.0
 >    38     1   1000.0  1000.0  1000.0
 >    39     1   1000.0  1000.0  1000.0
 >    40     1   1000.0  1000.0  1000.0
 >    41     1   1000.0  1000.0  1000.0
 >    42     1   1000.0  1000.0  1000.0
 >    43     1   1000.0  1000.0  1000.0
 >    44     1   1000.0  1000.0  1000.0
 >    45     1   1000.0  1000.0  1000.0
 >    46     1   1000.0  1000.0  1000.0
 >#endif
 >
 >Is my 1-4 scaling correct? I am confused about my topologies. Please help.
 >
 >
 >Ms. Anindita Gayen
 >
 >C/O Dr. Chaitali Mukhopadhyay
 >
 >Senior Research Fellow
 >
 >University of Calcutta
 >




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