[gmx-users] OPLS-AA topologies for ATP/ADP.

TJ Piggot t.piggot at bristol.ac.uk
Thu Feb 26 23:16:00 CET 2009


Sorry realised I posted the amber ATP link wrong, it is without the ) at 
the end:

http://www.pharmacy.manchester.ac.uk/bryce/amber

Tom

--On Thursday, February 26, 2009 17:15:22 +0000 TJ Piggot 
<t.piggot at bristol.ac.uk> wrote:

> Some of these charges look a bit suspect to me (eg the charge on the
> gamma phosphate). If you do not need to use OPLS then there is ATP
> included in the (united atom) gromos forcefields (see the top folder) and
> also ATP parameters available for the (all atom) Amber forcefields (see
> http://www.pharmacy.manchester.ac.uk/bryce/amber), all you have to do is
> convert them into a gromacs format
>
> Tom
>
> --On Thursday, February 26, 2009 08:33:06 -0800 "Bruce D. Ray"
> <brucedray at yahoo.com> wrote:
>
>>
>> On Wednesday, February 25, 2009 12:06:20 AM, Lucio Ricardo Montero
>> Valenzuela
>>
>> <lucioric at ibt.unam.mx> wrote:
>>
>>> Does anybody have the topology files for ATP and/or ADP for the OPLS-AA
>>> forcefield?. If not, how can I parameterize this molecules?.
>>> Best regards.
>>>    Lucio Montero.
>>>
>>> Lucio Ricardo Montero Valenzuela
>>> Instituto de Biotecnologia, UNAM
>>> Departamento de Biologia Molecular de Plantas
>>> Av. Universidad 2001, Col. Chamilpa
>>> Cuernavaca 62210
>>> Mexico
>>
>> I've not tested this at all, but from my attempts to add OPLS-AA to
>> topolbuild, I get the following that might be suitable for insertion in
>> the oplsaa rtp:
>>
>> [ ATP ]
>>  [ atoms ]
>>    O9P    opls_441  -0.635     0 ;O2
>>    O8P    opls_441  -0.635     1 ;O2
>>    O7P    opls_441  -0.635     2 ;O2
>>     PG    opls_445   0.072     3 ;P
>>    O6P    opls_442  -0.286     4 ;OS
>>    O5P    opls_441  -0.516     5 ;O2
>>    O4P    opls_441  -0.516     6 ;O2
>>     PB    opls_440   0.280     7 ;P
>>    O3P    opls_442  -0.250     8 ;OS
>>    O2P    opls_441  -0.516     9 ;O2
>>    O1P    opls_441  -0.516    10 ;O2
>>     PA    opls_440   0.276    11 ;P
>>    O5*    opls_442  -0.315    12 ;OS
>>    C5*    opls_443   0.085    13 ;CT
>>   H5*1    opls_444   0.059    14 ;HC
>>   H5*2    opls_444   0.059    15 ;HC
>>    C4*    opls_174   0.113    16 ;CT
>>    H4*    opls_176   0.065    17 ;HC
>>    O4*    opls_186  -0.348    18 ;OS
>>    C1*    opls_193   0.160    19 ;CO
>>    H1*    opls_194   0.084    20 ;HC
>>     N9    opls_354B -0.245    21 ;NA
>>     C8    opls_353   0.092    22 ;CK
>>     H8    opls_359   0.100    23 ;H5
>>     N7    opls_352  -0.233    24 ;NB
>>     C5    opls_350   0.145    25 ;CB
>>     C6    opls_351   0.147    26 ;CA
>>     N6    opls_356  -0.341    27 ;N2
>>    H61    opls_357   0.144    28 ;H
>>    H62    opls_358   0.144    29 ;H
>>     N1    opls_346  -0.219    30 ;NC
>>     C2    opls_347   0.120    31 ;CQ
>>     H2    opls_355   0.066    32 ;H5
>>     N3    opls_348  -0.218    33 ;NC
>>     C4    opls_349   0.159    34 ;CB
>>    C2*    opls_174   0.127    35 ;CT
>>    H2*    opls_176   0.100    36 ;HC
>>    O2'    opls_171  -0.385    37 ;OH
>>    H2'    opls_172   0.210    38 ;HO
>>    C3*    opls_174   0.113    39 ;CT
>>    H3*    opls_176   0.065    40 ;HC
>>    O3'    opls_171  -0.386    41 ;OH
>>    H3'    opls_172   0.210    42 ;HO
>>  [ bonds ]
>>     PG   O9P
>>     PG   O8P
>>     PG   O7P
>>    O6P    PG
>>     PB   O6P
>>     PB   O5P
>>     PB   O4P
>>    O3P    PB
>>     PA   O3P
>>     PA   O2P
>>     PA   O1P
>>     PA   O5*
>>    O5*   C5*
>>    C5*   C4*
>>    C5*  H5*1
>>    C5*  H5*2
>>    C4*   O4*
>>    C4*   H4*
>>    C4*   C3*
>>    O4*   C1*
>>    C1*    N9
>>    C1*   H1*
>>    C1*   C2*
>>     N9    C8
>>     C8    H8
>>     C8    N7
>>     N7    C5
>>     C5    C6
>>     C5    C4
>>     C6    N6
>>     N6   H61
>>     N6   H62
>>     C6    N1
>>     N1    C2
>>     C2    H2
>>     C2    N3
>>     N3    C4
>>     C4    N9
>>    C2*   C3*
>>    C2*   H2*
>>    C2*   O2'
>>    O2'   H2'
>>    C3*   H3*
>>    C3*   O3'
>>    O3'   H3'
>>
>>
>> Please let me know if this actually works for computations.
>> Charges were derived from the .mol2 file generated by Sybyl.
>>
>>
>> Sincerely,
>>
>>
>> --
>> Bruce D. Ray, Ph.D.
>> Associate Scientist
>> IUPUI
>> Physics Dept.
>> 402 N. Blackford St.
>> Indianapolis, IN  46202-3273
>>
>>
>>
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>
>
>
> ----------------------
> TJ Piggot
> t.piggot at bristol.ac.uk
> University of Bristol, UK.
>
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----------------------
TJ Piggot
t.piggot at bristol.ac.uk
University of Bristol, UK.




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