[gmx-users] topology of HEO compound in .rtp for G96 ff

Egidijus Kuprusevicius ekuprusevicius at yahoo.com
Thu May 21 20:27:32 CEST 2009


Hello, could anyone help me and check if the topology of the HEO compound was done properly for G96 ff? Thanks in advance. I couldn't find it in the database, so I decided to try to make it manualy. Any comments would be appreciated. Or maybe does exists any programs who does the work?


[ HEO ]
 [ atoms ]
   FE    FE     0.40000     0
   NA    NR    -0.10000     0
   NB    NR    -0.10000     0
   NC    NR    -0.10000     0
   ND    NR    -0.10000     0
  CHA   CH1     0.00000     1
  C1A     C     0.00000     2
  C2A     C     0.00000     2
  C3A     C     0.00000     2
  C4A     C     0.00000     2
  CMA   CH3     0.00000     3
  CAA   CH2     0.00000     4
  CBA   CH2     0.00000     4
  CGA     C     0.27000     5
  O1A    OM    -0.63500     5
  O2A    OM    -0.63500     5
  CHB   CH1     0.00000     6
  C1B     C     0.00000     7
  C2B     C     0.00000     7
  C3B     C     0.00000     7
  C4B     C     0.00000     7
  CMB   CH3     0.00000     8
  C11     C     0.38000     9 
  O11     O    -0.38000     9
  CHC   CH1     0.00000    10
  C1C     C     0.00000    11
  C2C     C     0.00000    11
  C3C     C     0.00000    11
  C4C     C     0.00000    11
  CMC   CH3     0.00000    12
  CAC   CR1     0.00000    13
  CBC   CH2     0.00000    13
  CHD   CH1     0.00000    14
  C1D     C     0.00000    15
  C2D     C     0.00000    15
  C3D     C     0.00000    15
  C4D     C     0.00000    15
  CMD   CH3     0.00000    16
  CAD   CH2     0.00000    17
  CBD   CH2     0.00000    17
  CGD     C     0.27000    18
  O1D    OM    -0.63500    18
  O2D    OM    -0.63500    18
  C12   CH2     0.00000    19 
  C13   CH2     0.00000    19
  C14   CH2     0.00000    20
  C15   CH1     0.00000    20
  C16   CH3     0.00000    20
  C17   CH2     0.00000    20
  C18   CH2     0.00000    21
  C19   CH2     0.00000    22
  C20   CH1     0.00000    22
  C21   CH3     0.00000    22
  C22   CH2     0.00000    22
  C23   CH2     0.00000    23
  C24   CH2     0.00000    24
  C25   CH1     0.00000    24
  C26   CH3     0.00000    24
  C27   CH3     0.00000    24
 [ bonds ]
   FE    NA    gb_34   
   FE    NB    gb_34   
   FE    NC    gb_34   
   FE    ND    gb_34   
   NA   C1A    gb_13   
   NA   C4A    gb_13   
   NB   C1B    gb_13   
   NB   C4B    gb_13   
   NC   C1C    gb_13   
   NC   C4C    gb_13   
   ND   C1D    gb_13   
   ND   C4D    gb_13       
  CHA   C1A    gb_16   
  CHA   C4D    gb_16   
  C1A   C2A    gb_16   
  C2A   C3A    gb_16   
  C2A   CAA    gb_26   
  C3A   C4A    gb_16   
  C3A   CMA    gb_26   
  C4A   CHB    gb_16   
  CAA   CBA    gb_26   
  CBA   CGA    gb_26   
  CGA   O1A    gb_5    
  CGA   O2A    gb_5        
  CHB   C1B    gb_16   
  C1B   C2B    gb_16   
  C2B   C3B    gb_16   
  C2B   CMB    gb_26   
  C3B   C4B    gb_16   
  C4B   CHC    gb_16      
  CHC   C1C    gb_16   
  C1C   C2C    gb_16   
  C2C   C3C    gb_16   
  C2C   CMC    gb_26   
  C3C   C4C    gb_16   
  C3C   CAC    gb_26   
  C4C   CHD    gb_16   
  CAC   CBC    gb_11       
  CHD   C1D    gb_16   
  C1D   C2D    gb_16   
  C2D   C3D    gb_16   
  C2D   CMD    gb_26   
  C3D   C4D    gb_16   
  C3D   CAD    gb_26   
  CAD   CBD    gb_26   
  CBD   CGD    gb_26   
  CGD   O1D    gb_5    
  CGD   O2D    gb_5  
  C3B   C11    gb_26   
  C11   O11    gb_4  
  C11   C12    gb_26 ; C, CHn  -   C, CHn    800
  C12   C13    gb_26 ; C, CHn  -   C, CHn    800
  C13   C14    gb_26 ; C, CHn  -   C, CHn    800
  C14   C15    gb_26 ; C, CHn  -   C, CHn    800
  C15   C16    gb_26 ; C, CHn  -   C, CHn    800
  C15   C17    gb_26 ; C, CHn  -   C, CHn    800
  C17   C18    gb_26 ; C, CHn  -   C, CHn    800
  C18   C19    gb_26 ; C, CHn  -   C, CHn    800
  C19   C20    gb_26 ; C, CHn  -   C, CHn    800
  C20   C21    gb_26 ; C, CHn  -   C, CHn    800
  C20   C22    gb_26 ; C, CHn  -   C, CHn    800
  C22   C23    gb_26 ; C, CHn  -   C, CHn    800
  C23   C24    gb_26 ; C, CHn  -   C, CHn    800
  C24   C25    gb_26 ; C, CHn  -   C, CHn    800
  C25   C26    gb_26 ; C, CHn  -   C, CHn    800
  C25   C27    gb_26 ; C, CHn  -   C, CHn    800   
 [ exclusions ]
;  ai    aj
   FE   CHA
   FE   C2A
   FE   C3A
   FE   CHB
   FE   C2B
   FE   C3B
   FE   CHC
   FE   C2C
   FE   C3C
   FE   CHD
   FE   C2D
   FE   C3D
   NA   CMA
   NA   CAA
   NA   C1B
   NA   C4B
   NA   C1C
   NA   C4C
   NA   C1D
   NA   C4D
   NB   C1A
   NB   C4A
   NB   CMB
   NB   C11 
   NB   C1C
   NB   C4C
   NB   C1D
   NB   C4D
   NC   C1A
   NC   C4A
   NC   C1B
   NC   C4B
   NC   CMC
   NC   CAC
   NC   C1D
   NC   C4D
   ND   C1A
   ND   C4A
   ND   C1B
   ND   C4B
   ND   C1C
   ND   C4C
   ND   CMD
   ND   CAD
  CHA   C3A
  CHA   C4A
  CHA   CAA
  CHA   C1D
  CHA   C2D
  CHA   CAD
  C1A   CMA
  C1A   CHB
  C1A   C3D
  C2A   CHB
  C3A   C1B
  C4A   CAA
  C4A   C2B
  CMA   CAA
  CMA   CHB
  CHB   C3B
  CHB   C4B
  CHB   CMB
  C1B   C11 
  C1B   CHC
  C2B   CHC
  C3B   C1C
  C4B   CMB
  C4B   C2C
  CMB   C11 
  C11   CHC 
  CHC   C3C
  CHC   C4C
  CHC   CMC
  C1C   CAC
  C1C   CHD
  C2C   CHD
  C3C   C1D
  C4C   CMC
  C4C   C2D
  CMC   CAC
  CAC   CHD
  CHD   C3D
  CHD   C4D
  CHD   CMD
  C1D   CAD
  C4D   CMD
  CMD   CAD
 [ angles ]
;  ai    aj    ak   gromos type
   NA    FE    NB     ga_1    
   NB    FE    NC     ga_1    
   NC    FE    ND     ga_1    
   NA    FE    ND     ga_1
   NA    FE    NC     ga_1  ; NR(heme)  -  FE  -  NR(heme)  100 
   NB    FE    ND     ga_1  ; NR(heme)  -  FE  -  NR(heme)  100 
   FE    NA   C1A     ga_35   
   FE    NA   C4A     ga_35   
  C1A    NA   C4A     ga_5    
   FE    NB   C1B     ga_35   
   FE    NB   C4B     ga_35   
  C1B    NB   C4B     ga_5    
   FE    NC   C1C     ga_35   
   FE    NC   C4C     ga_35   
  C1C    NC   C4C     ga_5    
   FE    ND   C1D     ga_35   
   FE    ND   C4D     ga_35   
  C1D    ND   C4D     ga_5       
  C1A   CHA   C4D     ga_36      
   NA   C1A   CHA     ga_32   
   NA   C1A   C2A     ga_14   
  CHA   C1A   C2A     ga_37   
  C1A   C2A   C3A     ga_6    
  C1A   C2A   CAA     ga_36   
  C3A   C2A   CAA     ga_36   
  C2A   C3A   C4A     ga_6    
  C2A   C3A   CMA     ga_36   
  C4A   C3A   CMA     ga_36   
   NA   C4A   C3A     ga_14   
   NA   C4A   CHB     ga_32   
  C3A   C4A   CHB     ga_37   
  C2A   CAA   CBA     ga_14   
  CAA   CBA   CGA     ga_14   
  CBA   CGA   O1A     ga_21   
  CBA   CGA   O2A     ga_21   
  O1A   CGA   O2A     ga_37      
  C4A   CHB   C1B     ga_36      
   NB   C1B   CHB     ga_32   
   NB   C1B   C2B     ga_14   
  CHB   C1B   C2B     ga_37   
  C1B   C2B   C3B     ga_6    
  C1B   C2B   CMB     ga_36   
  C3B   C2B   CMB     ga_36   
  C2B   C3B   C4B     ga_6    
   NB   C4B   C3B     ga_14   
   NB   C4B   CHC     ga_32   
  C3B   C4B   CHC     ga_37      
  C4B   CHC   C1C     ga_36     
   NC   C1C   CHC     ga_32   
   NC   C1C   C2C     ga_14   
  CHC   C1C   C2C     ga_37   
  C1C   C2C   C3C     ga_6    
  C1C   C2C   CMC     ga_36   
  C3C   C2C   CMC     ga_36   
  C2C   C3C   C4C     ga_6    
  C2C   C3C   CAC     ga_36   
  C4C   C3C   CAC     ga_36   
   NC   C4C   C3C     ga_14   
   NC   C4C   CHD     ga_32   
  C3C   C4C   CHD     ga_37   
  C3C   CAC   CBC     ga_36     
  C4C   CHD   C1D     ga_36      
   ND   C1D   CHD     ga_32   
   ND   C1D   C2D     ga_14   
  CHD   C1D   C2D     ga_37   
  C1D   C2D   C3D     ga_6    
  C1D   C2D   CMD     ga_36   
  C3D   C2D   CMD     ga_36   
  C2D   C3D   C4D     ga_6    
  C2D   C3D   CAD     ga_36   
  C4D   C3D   CAD     ga_36   
   ND   C4D   CHA     ga_32   
   ND   C4D   C3D     ga_14   
  CHA   C4D   C3D     ga_37   
  C3D   CAD   CBD     ga_14   
  CAD   CBD   CGD     ga_14   
  CBD   CGD   O1D     ga_21   
  CBD   CGD   O2D     ga_21   
  O1D   CGD   O2D     ga_37 
  C3B   C11   O11     ga_29 ; O  -  C  -  CHn, C    120
  C3B   C11   C12     ga_29 ; O  -  C  -  CHn, C    120
  C12   C11   O11     ga_29 ; O  -  C  -  CHn, C    120  
  C2B   C3B   C11     ga_36 ; X(noH)  - 5-ring      100  
  C4B   C3B   C11     ga_36 ; X(noH)  - 5-ring      100  
  C11   C12   C13     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C12   C13   C14     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C13   C14   C15     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C14   C15   C16     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C14   C15   C17     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C16   C15   C17     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C15   C17   C18     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C17   C18   C19     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C18   C19   C20     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C19   C20   C21     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C19   C20   C22     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C21   C20   C22     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C20   C22   C23     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110
  C22   C23   C24     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C23   C24   C25     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C24   C25   C26     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C24   C25   C27     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  C26   C25   C27     ga_14 ; CHn  -  CHn  -  C, CHn, OA, NR, NT, NL        110 
  [ impropers ]
;  ai    aj    ak    al   gromos type
   FE   C1A   C4A    NA     gi_3    
   FE   C1B   C4B    NB     gi_3    
   FE   C1C   C4C    NC     gi_3    
   FE   C1D   C4D    ND     gi_3    
  CHA    NA   C2A   C1A     gi_1    
  CHB    NA   C3A   C4A     gi_1    
  CHB    NB   C2B   C1B     gi_1    
  CHC    NB   C3B   C4B     gi_1    
  CHC    NC   C2C   C1C     gi_1    
  CHD    NC   C3C   C4C     gi_1    
  CHD    ND   C2D   C1D     gi_1    
  CHA    ND   C3D   C4D     gi_1    
  C2A   C1A   C3A   CAA     gi_1    
  C3A   C2A   C4A   CMA     gi_1    
  C2B   C1B   C3B   CMB     gi_1   ; planar groups 40    
  C3B   C2B   C4B   C11     gi_1   ; planar groups 40    
  C2C   C1C   C3C   CMC     gi_1    
  C3C   C2C   C4C   CAC     gi_1    
  C2D   C1D   C3D   CMD     gi_1    
  C3D   C2D   C4D   CAD     gi_1    
  CBA   O1A   O2A   CGA     gi_1    
  CBD   O1D   O2D   CGD     gi_1      
   NA   C1A   C2A   C3A     gi_1    
  C1A   C2A   C3A   C4A     gi_1    
  C2A   C3A   C4A    NA     gi_1    
  C1A    NA   C4A   C3A     gi_1    
  C2A   C1A    NA   C4A     gi_1    
   NB   C1B   C2B   C3B     gi_1    
  C1B   C2B   C3B   C4B     gi_1    
   NB   C4B   C3B   C2B     gi_1    
  C4B    NB   C1B   C2B     gi_1    
  C1B    NB   C4B   C3B     gi_1    
   NC   C1C   C2C   C3C     gi_1    
  C1C   C2C   C3C   C4C     gi_1    
   NC   C4C   C3C   C2C     gi_1    
  C4C    NC   C1C   C2C     gi_1    
  C1C    NC   C4C   C3C     gi_1    
   ND   C1D   C2D   C3D     gi_1    
  C1D   C2D   C3D   C4D     gi_1    
   ND   C4D   C3D   C2D     gi_1    
  C4D    ND   C1D   C2D     gi_1    
  C1D    ND   C4D   C3D     gi_1  
  C11   C3B   C12   O11     gi_1   ; planar groups 40
  C3B   C4B   C2B   C11     gi_1   ; planar groups 40
  C15   C17   C16   C14     gi_2   ; tetrahedral centres 80
  C20   C22   C21   C19     gi_2   ; tetrahedral centres 80
  C25   C27   C26   C24     gi_2   ; tetrahedral centres 80
 [ dihedrals ]
;  ai    aj    ak    al   gromos type
   NA   C4A   CHB   C1B     gd_5    
  C4A   CHB   C1B    NB     gd_5    
   NB   C4B   CHC   C1C     gd_5    
  C4B   CHC   C1C    NC     gd_5    
   NC   C4C   CHD   C1D     gd_5    
  C4C   CHD   C1D    ND     gd_5    
   ND   C4D   CHA   C1A     gd_5    
  C4D   CHA   C1A    NA     gd_5    
  C1A   C2A   CAA   CBA     gd_20   
  C2A   CAA   CBA   CGA     gd_17   
  CAA   CBA   CGA   O1A     gd_20      
  C2C   C3C   CAC   CBC     gd_3
  C2D   C3D   CAD   CBD     gd_20   
  C3D   CAD   CBD   CGD     gd_17   
  CAD   CBD   CGD   O1D     gd_20   
  ND    FE    NA   C1A       0       0       4
  NA    FE    NB   C1B       0       0       4
  NB    FE    NC   C1C       0       0       4
  NC    FE    ND   C1D       0       0       4
  C2B   C3B   C11   O11     gd_20   ; -CHn-C,NR (ring), CR1-        0.24
  C3B   C11   C12   C13     gd_20   ; -CHn-C,NR (ring), CR1-        0.24
  C27   C25   C24   C23     gd_17   ; -CHn,SI-CHn-  1.4   
  C26   C25   C24   C23     gd_17   ; -CHn,SI-CHn-  1.4
  C25   C24   C23   C22     gd_17   ; -CHn,SI-CHn-  1.4   
  C24   C23   C22   C20     gd_17   ; -CHn,SI-CHn-  1.4
  C23   C22   C20   C19     gd_17   ; -CHn,SI-CHn-  1.4   
  C22   C20   C19   C18     gd_17   ; -CHn,SI-CHn-  1.4
  C21   C20   C19   C18     gd_17   ; -CHn,SI-CHn-  1.4   
  C20   C19   C18   C17     gd_17   ; -CHn,SI-CHn-  1.4
  C19   C18   C17   C15     gd_17   ; -CHn,SI-CHn-  1.4   
  C18   C17   C15   C14     gd_17   ; -CHn,SI-CHn-  1.4
  C17   C15   C14   C13     gd_17   ; -CHn,SI-CHn-  1.4   
  C16   C15   C14   C13     gd_17   ; -CHn,SI-CHn-  1.4  
  C15   C14   C13   C12     gd_17   ; -CHn,SI-CHn-  1.4   
  C14   C13   C12   C11     gd_17   ; -CHn,SI-CHn-  1.4

Egis 



      



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