[gmx-users] Error in ligand coordinate file

sai nitin sainitin7 at gmail.com
Wed Aug 8 16:44:44 CEST 2012


Hi justin,

Ok i will explain more clearly what i really  have is protein ligand
complex from Autodock..I choose best complex based on predicted
binding affinity. Using pymol i visualized complex.pdb and saved only
ligand (ligand.pdb given below) and used swiss param tool online
http://swissparam.ch/ to charmm 27 FF .itp file then i followed
tutorial and ran 10ns simulation now wanted to use g_lie to calculate
binding free energies..of this complex..so have to run one more
simulation for ligand only in water right...for that im using
coordinate file which i have saved it from pymol
in original PDB file it is properly aligned :)

ATOM      1  C   <1> d          83.432  21.209  56.133 -0.07 -0.02           C
ATOM      2  C   <1> d          84.828  21.291  56.786 -0.29  0.00           C
ATOM      3  O   <1> d          83.629  21.200  54.697 -0.02 -0.07           O
ATOM      4  C   <1> d          85.679  20.564  55.751 -0.19 -0.02           C
ATOM      5  C   <1> d          85.046  21.032  54.436 -0.15  0.04           C
ATOM      6  N   <1> d          82.546  22.305  56.532 -0.10 -0.05           N
ATOM      7  C   <1> d          81.884  22.186  57.757  0.18  0.05           C
ATOM      8  N   <1> d          81.028  23.185  58.155  0.01 -0.07           N
ATOM      9  O   <1> d          82.069  21.213  58.493 -0.09  0.04           O
ATOM     10  C   <1> d          80.868  24.232  57.405 -0.07  0.06           C
ATOM     11  C   <1> d          81.567  24.413  56.119 -0.49  0.00           C
ATOM     12  C   <1> d          82.377  23.424  55.745 -0.38  0.02           C
ATOM     13  N   <1> d          80.012  25.195  57.842  0.39  0.02           N
ATOM     14  H   <1> d          79.062  24.997  58.139 -0.05 -0.06           H
ATOM     15  H   <1> d          80.312  26.164  57.884 -0.11 -0.01           H
ATOM     16  O   <1> d          84.944  20.703  58.090  0.01  0.19           O
ATOM     17  H   <1> d          85.311  19.798  57.956 -0.17 -0.58           H
ATOM     18  O   <1> d          85.512  19.135  55.900  0.09  0.57           O
ATOM     19  H   <1> d          84.884  19.014  56.648 -0.30 -0.75           H
ATOM     20  C   <1> d          85.627  22.354  53.918 -0.22  0.11           C
ATOM     21  O   <1> d          84.597  23.194  53.394 -0.56 -0.44           O
ATOM     22  H   <1> d          83.757  22.697  53.521  0.27  0.18           H
END

Im running PDB2GMX to generate topol.top file..for this ligand by
CHARMM 27 FF but it gives following error

Fatal error:
Residue '<1>' not found in residue topology database

So now question how to solve this error..? Can you please suggest some help ?

thanks,
Nitin


On Wed, Aug 8, 2012 at 12:08 PM, Justin Lemkul <jalemkul at vt.edu> wrote:
>
>
> On 8/8/12 5:37 AM, sai nitin wrote:
>>
>> Hi justin,
>>
>> Thanks for reply now i have ligand corrdinate file as follows
>>
>> ATOM      1  N   A         -13.006 -12.965  -0.251 -0.60 -0.09           N
>> ATOM      2  C   A         -13.386 -13.020   1.035 -0.38  0.03           C
>> ATOM      3  C   A         -13.037 -14.131   1.869 -0.32 -0.03           C
>> ATOM      4  C   A         -12.284 -14.007  -0.761 -0.21  0.02           C
>> ATOM      5  N   A         -11.897 -15.079   0.059 -0.24 -0.01           N
>> ATOM      6  C   A         -12.288 -15.172   1.391 -0.37  0.01           C
>> ATOM      7  N   A         -13.547 -13.886   3.036 -0.34  0.14           N
>> ATOM      8  N   A         -14.076 -12.193   1.759 -0.27  0.01           N
>> ATOM      9  C   A         -14.163 -12.729   2.956 -0.29 -0.08           C
>> ATOM     10  N   A         -11.887 -13.919  -2.092 -0.05  0.04           N
>> ATOM     11  H   A         -11.305 -15.802  -0.326 -0.11 -0.03           H
>> ATOM     12  H   A         -12.027 -12.978  -2.454 -0.07 -0.16           H
>> ATOM     13  C   A         -11.368 -14.845  -3.008 -0.39  0.00           C
>> ATOM     14  C   A         -11.534 -14.731  -4.394 -0.49  0.00           C
>> ATOM     15  C   A         -11.032 -15.710  -5.270 -0.32  0.00           C
>> ATOM     16  C   A         -10.360 -16.822  -4.750 -0.24  0.00           C
>> ATOM     17  C   A         -10.189 -16.950  -3.375 -0.33  0.00           C
>> ATOM     18  C   A         -10.690 -15.970  -2.515 -0.42  0.00           C
>> ATOM     19  C   A         -11.203 -15.559  -6.724 -0.27  0.00           C
>> ATOM     20  C   A         -12.302 -15.958  -7.389 -0.19  0.02           C
>> ATOM     21  O   A         -11.918 -16.240   2.152 -0.14 -0.09           O
>> ATOM     22  H   A         -11.168 -16.702   1.710 -0.26 -0.13           H
>> END
>>
>> Still not working
>>
>> Fatal error:
>> Atom N in residue A 0 was not found in rtp entry RA with 32 atoms
>> while sorting atoms.
>>
>
> Your molecule has to correspond to some known entity in the force field.
> Here, with the residue name "A," the closest match pdb2gmx can find is to
> the ribonucleotide RA.  If that's what this is, then your atom names need to
> match with what is expected.
>
> It also appears your columns are still misaligned.
>
> -Justin
>
>
>> Any help ??
>>
>> Thanks,
>> Nitin
>>
>> On Tue, Aug 7, 2012 at 11:42 AM, Justin Lemkul <jalemkul at vt.edu> wrote:
>>>
>>>
>>>
>>> On 8/7/12 5:08 AM, sai nitin wrote:
>>>>
>>>>
>>>> Hi all,
>>>>
>>>> Recently i performed protein ligand complex simulation my aim is to
>>>> compute free energy values using g_lie..i came across that to perform
>>>> g_lie analysis one should two 2 MD simulation one is protein ligand
>>>> complex simulation (this is done ) used Charmm 27 FF second one is
>>>> simulate ligand in water...which is the step i got stuck i know it is
>>>> simple but couldnt get through first step  it self preparing ligand
>>>> coordinate file which i already have as follows i ran PDB2gmx to
>>>> generate topol.top file but couldnt succeed.. ligand coordinate file
>>>> is given below
>>>>
>>>> ATOM      1  N   -13.006 -12.965  -0.251  1.00  0.00           N
>>>> ATOM      2  C   -13.386 -13.020   1.035  1.00  0.00           C
>>>> ATOM      3  C1  -13.037 -14.131   1.869  1.00  0.00           C
>>>> ATOM      4  C2  -12.284 -14.007  -0.761  1.00  0.00           C
>>>> ATOM      5  N1  -11.897 -15.079   0.059  1.00  0.00           N
>>>> ATOM      6  C3  -12.288 -15.172   1.391  1.00  0.00           C
>>>> ATOM      7  N2  -13.547 -13.886   3.036  1.00  0.00           N
>>>> ATOM      8  N3  -14.076 -12.193   1.759  1.00  0.00           N
>>>> ATOM      9  C4  -14.163 -12.729   2.956  1.00  0.00           C
>>>> ATOM     10  N4  -11.887 -13.919  -2.092  1.00  0.00           N
>>>> ATOM     11  H   -11.305 -15.802  -0.326  1.00  0.00           H
>>>> ATOM     12  H1  -12.027 -12.978  -2.454  1.00  0.00           H
>>>> ATOM     13  C5  -11.368 -14.845  -3.008  1.00  0.00           C
>>>> ATOM     14  C6  -11.534 -14.731  -4.394  1.00  0.00           C
>>>> ATOM     15  C7  -11.032 -15.710  -5.270  1.00  0.00           C
>>>> ATOM     16  C8  -10.360 -16.822  -4.750  1.00  0.00           C
>>>> ATOM     17  C9  -10.189 -16.950  -3.375  1.00  0.00           C
>>>> ATOM     18  C10 -10.690 -15.970  -2.515  1.00  0.00           C
>>>> ATOM     19  C11 -11.203 -15.559  -6.724  1.00  0.00           C
>>>> ATOM     20  C12 -12.302 -15.958  -7.389  1.00  0.00           C
>>>> ATOM     21  O   -11.918 -16.240   2.152  1.00  0.00           O
>>>> ATOM     22  H2  -11.168 -16.702   1.710  1.00  0.00           H
>>>> ATOM     23  H3  -14.661 -12.289   3.746  1.00  0.00           H
>>>> ATOM     24  H4  -12.034 -13.914  -4.779  1.00  0.00           H
>>>> ATOM     25  H5  -9.992 -17.547  -5.386  1.00  0.00            H
>>>> ATOM     26  H6  -9.692 -17.769  -2.991  1.00  0.00            H
>>>> ATOM     27  H7  -10.559 -16.076  -1.497  1.00  0.00           H
>>>> ATOM     28  H8  -10.438 -15.123  -7.263  1.00  0.00           H
>>>> ATOM     29  H9  -13.084 -16.397  -6.878  1.00  0.00           H
>>>> ATOM     30  H10 -12.364 -15.825  -8.411  1.00  0.00           H
>>>>
>>>>
>>>> Running PDB2gmx gives error as follows
>>>>
>>>> Fatal error:
>>>> Residue '-13.' not found in residue topology database
>>>>
>>>>
>>>> Can any tell me what is wrong in my coordinate file ....
>>>>
>>>
>>> It is formatted incorrectly.  PDB format requires fixed spacing and
>>> correct
>>> content.  The file shown above lacks a residue name column.
>>>
>>> -Justin
>>>
>>> --
>>> ========================================
>>>
>>> Justin A. Lemkul, Ph.D.
>>> Research Scientist
>>> Department of Biochemistry
>>> Virginia Tech
>>> Blacksburg, VA
>>> jalemkul[at]vt.edu | (540) 231-9080
>>> http://www.bevanlab.biochem.vt.edu/Pages/Personal/justin
>>>
>>> ========================================
>>> --
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>>
>>
>>
>>
>
> --
> ========================================
>
> Justin A. Lemkul, Ph.D.
> Research Scientist
> Department of Biochemistry
> Virginia Tech
> Blacksburg, VA
> jalemkul[at]vt.edu | (540) 231-9080
> http://www.bevanlab.biochem.vt.edu/Pages/Personal/justin
>
> ========================================
> --
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-- 

Sainitin D
PhD student
Bioinformatics Group
Biotechnology Center
Technische Universität Dresden
Tatzberg 47/49
01307 Dresden, Germany
Tel Lab:+49 (0)351 463 40060



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