[gmx-users] GROMOS 54a7 mapping warning

Gselman, Larissa larissa.gselman at rwth-aachen.de
Thu Aug 1 12:25:44 CEST 2019


Thank you for your answer! I used the Yasara -> Edit -> Clean Option and it added atoms (1H, 2H and 3H for ASP and OXT for ASN) to my pdb file.


Nevertheless, I still get the same warnings when I try with -ignh. I cannot see that there are other atoms missing?


When I try without -ignh, I even get a fatal error which says: Atom HA in residue ASP 1 was not found in rtp entry ASP with 11 atoms while sorting atoms.


When I look into the aminoacids.rtp file from the GROMOS 54a7 force field it looks like this:

[ ASP ]
 [ atoms ]
    N     N        -0.31000     0
    H     H          0.31000     0
    CA   CH1     0.00000     1
    CB   CH2     0.00000     1
    CG     C        0.27000     2
    OD1    OM    -0.63500     2
     OD2    OM    -0.63500     2
    C     C       0.450     3
    O     O      -0.450     3



Here are my first and last amino acids from the new pdb file with the added atoms:


ATOM      1  N   ASP A   1      59.994  60.432  82.286  1.00  7.49           N
ATOM      2 1H   ASP A   1      60.547  59.791  81.754  1.00  7.49           H
ATOM      3 2H   ASP A   1      59.319  59.903  82.801  1.00  7.49           H
ATOM      4 3H   ASP A   1      60.596  60.885  82.944  1.00  7.49           H
ATOM      5  CA  ASP A   1      59.341  61.407  81.415  1.00  7.49           C
ATOM      6  HA  ASP A   1      58.651  60.833  80.799  1.00  7.49           H
ATOM      7  C   ASP A   1      60.313  62.117  80.435  1.00  7.49           C
ATOM      8  O   ASP A   1      61.524  61.881  80.391  1.00  7.49           O
ATOM      9  CB  ASP A   1      58.494  62.384  82.263  1.00  7.49           C
ATOM     10 1HB  ASP A   1      58.142  61.868  83.157  1.00  7.49           H
ATOM     11 2HB  ASP A   1      59.114  63.222  82.584  1.00  7.49           H
ATOM     12  CG  ASP A   1      57.247  62.920  81.535  1.00  7.49           C
ATOM     13  OD1 ASP A   1      57.107  62.729  80.305  1.00  7.49           O
ATOM     14  OD2 ASP A   1      56.369  63.525  82.180  1.00  7.49           O
.

.

.

ATOM    626  N   ASN A  38      49.792  47.722  37.078  1.00 13.81           N
ATOM    627  H   ASN A  38      50.649  48.244  36.922  1.00 13.81           H
ATOM    628  CA  ASN A  38      48.636  48.172  36.306  1.00 13.81           C
ATOM    629  HA  ASN A  38      48.705  49.256  36.233  1.00 13.81           H
ATOM    630  C   ASN A  38      47.283  47.875  36.982  1.00 13.81           C
ATOM    631  O   ASN A  38      47.185  47.311  38.072  1.00 13.81           O
ATOM    632  OXT ASN A  38      46.199  48.179  36.482  1.00 13.81           O
ATOM    633  CB  ASN A  38      48.757  47.594  34.881  1.00 13.81           C
ATOM    634 1HB  ASN A  38      47.934  47.954  34.264  1.00 13.81           H
ATOM    635 2HB  ASN A  38      49.688  47.938  34.433  1.00 13.81           H
ATOM    636  CG  ASN A  38      48.756  46.074  34.842  1.00 13.81           C
ATOM    637  OD1 ASN A  38      49.775  45.434  34.642  1.00 13.81           O
ATOM    638  ND2 ASN A  38      47.621  45.445  35.027  1.00 13.81           N
ATOM    639 1HD2 ASN A  38      47.668  44.445  35.083  1.00 13.81           H
ATOM    640 2HD2 ASN A  38      46.815  45.983  35.313  1.00 13.81           H
TER     641      ASN A  38
END


Thank you so much for your help.

________________________________
Von: gromacs.org_gmx-users-bounces at maillist.sys.kth.se <gromacs.org_gmx-users-bounces at maillist.sys.kth.se> im Auftrag von David van der Spoel <spoel at xray.bmc.uu.se>
Gesendet: Mittwoch, 31. Juli 2019 21:21:39
An: gmx-users at gromacs.org
Betreff: Re: [gmx-users] GROMOS 54a7 mapping warning

Den 2019-07-31 kl. 15:21, skrev Gselman, Larissa:
> Hallo everyone,
>
>
> I want to simulate a peptide with the Gromos 54a7 force field.
Your structure is missing atoms, please fix and rerun without -ignh.
>
>
> So, my first command is:
>
> gmx_mpi pdb2gmx -f Mh.pdb -o Mh_processed.gro -water spce -ignh -inter
>
> I choose 14 for the Gromos 54a7 ff, then I choose the protonation state the titratable amino acids and for the termini I choose the zwitterionic state (so I choose 0 and 0).
>
> But this results in the following warnings:
>
> WARNING: WARNING: Residue 1 named ASP of a molecule in the input file was mapped to an entry in the topology database, but the atom H used in an interaction of type angle in that entry is not found in the input file. Perhaps your atom and/or residue naming needs to be fixed.
>
> WARNING: WARNING: Residue 38 named ASN of a molecule in the input file was mapped to an entry in the topology database, but the atom O used in an interaction of type angle in that entry is not found in the input file. Perhaps your atom and/or residue naming needs to be fixed.
>
>
> This is the beginning and end of my pdb file with ASP as first and ASN as last amino acid:
>
> ATOM      1  N   ASP A   1      59.994  60.432  82.286  1.00  7.49
> ATOM      2  CA  ASP A   1      59.341  61.407  81.415  1.00  7.49
> ATOM      3  HA  ASP A   1      58.651  60.833  80.799  1.00  7.49
> ATOM      4  CB  ASP A   1      58.494  62.384  82.263  1.00  7.49
> ATOM      5  HB1 ASP A   1      59.114  63.222  82.584  1.00  7.49
> ATOM      6  HB2 ASP A   1      58.142  61.868  83.157  1.00  7.49
> ATOM      7  CG  ASP A   1      57.247  62.920  81.535  1.00  7.49
> ATOM      8  OD1 ASP A   1      57.107  62.729  80.305  1.00  7.49
> ATOM      9  OD2 ASP A   1      56.369  63.525  82.180  1.00  7.49
> ATOM     10  C   ASP A   1      60.313  62.117  80.435  1.00  7.49
> ATOM     11  O   ASP A   1      61.524  61.881  80.391  1.00  7.49
> .
> .
> .
> ATOM    623  N   ASN A  38      49.792  47.722  37.078  1.00 13.81
> ATOM    624  H   ASN A  38      50.649  48.244  36.922  1.00 13.81
> ATOM    625  CA  ASN A  38      48.636  48.172  36.306  1.00 13.81
> ATOM    626  HA  ASN A  38      48.705  49.256  36.233  1.00 13.81
> ATOM    627  CB  ASN A  38      48.757  47.594  34.881  1.00 13.81
> ATOM    628  HB1 ASN A  38      49.688  47.938  34.433  1.00 13.81
> ATOM    629  HB2 ASN A  38      47.934  47.954  34.264  1.00 13.81
> ATOM    630  CG  ASN A  38      48.756  46.074  34.842  1.00 13.81
> ATOM    631  OD1 ASN A  38      49.775  45.434  34.642  1.00 13.81
> ATOM    632  ND2 ASN A  38      47.621  45.445  35.027  1.00 13.81
> ATOM    633 1HD2 ASN A  38      46.815  45.983  35.313  1.00 13.81
> ATOM    634 2HD2 ASN A  38      47.668  44.445  35.083  1.00 13.81
> ATOM    635  C   ASN A  38      47.283  47.875  36.982  1.00 13.81
> ATOM    636  O   ASN A  38      47.185  47.311  38.072  1.00 13.81
> TER
>
>
> I hope you can help me and maybe tell me why this problem occurs and what I have to change. Thank you very much!
>
> Best regards
> Larissa
>


--
David van der Spoel, Ph.D., Professor of Biology
Head of Department, Cell & Molecular Biology, Uppsala University.
Box 596, SE-75124 Uppsala, Sweden. Phone: +46184714205.
http://www.icm.uu.se
--
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